Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate

Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate

In the title compound, K+·C6H8NO4−, the K+ cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methylene groups of the anions are always directed towards the coordinated potassium cations. The N—C&#8212...

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Main Authors: Cédric Reuter, Jörg M. Neudörfl, Hans-Günther Schmalz
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810010159
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spelling doaj-0024eeef8ce84cd7a7d23fa94fa3d4572020-11-25T03:34:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m461m46110.1107/S1600536810010159Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinateCédric ReuterJörg M. NeudörflHans-Günther SchmalzIn the title compound, K+·C6H8NO4−, the K+ cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methylene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound. http://scripts.iucr.org/cgi-bin/paper?S1600536810010159
collection DOAJ
language English
format Article
sources DOAJ
author Cédric Reuter
Jörg M. Neudörfl
Hans-Günther Schmalz
spellingShingle Cédric Reuter
Jörg M. Neudörfl
Hans-Günther Schmalz
Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
Acta Crystallographica Section E
author_facet Cédric Reuter
Jörg M. Neudörfl
Hans-Günther Schmalz
author_sort Cédric Reuter
title Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
title_short Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
title_full Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
title_fullStr Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
title_full_unstemmed Potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
title_sort potassium (1-methoxycarbonyl-2-methylprop-2-en-2-ylidene)azinate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description In the title compound, K+·C6H8NO4−, the K+ cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methylene groups of the anions are always directed towards the coordinated potassium cations. The N—C—C—C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810010159
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