Reduction of Magnetite in the Presence of Activated Carbon Using Mechanical Alloying

The reduction behaviour of magnetite using graphite under ball-milling conditions (using a planetary mono mill, Fritsch Pulverisette 6) has been investigated. The reaction of magnetite and graphite at different milling conditions leads to the formation of Fe2+ and Fe3+ species, the former increasing...

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Bibliographic Details
Main Authors: Ledwaba Harry Moloto, Sunnyboy Stanley Manzini, Ezekiel Dixon Dikio
Format: Article
Language:English
Published: Hindawi Limited 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/837649
Description
Summary:The reduction behaviour of magnetite using graphite under ball-milling conditions (using a planetary mono mill, Fritsch Pulverisette 6) has been investigated. The reaction of magnetite and graphite at different milling conditions leads to the formation of Fe2+ and Fe3+ species, the former increasing at the expense of Fe3O4. Fe3O4 completely disappeared after a ball to powder ratio of 50 : 1 and beyond. The Fe2+ species were confirmed to be due to FeO using Mössbauer Spectroscopy and X-ray diffraction techniques. Scanning electron microscopy and transmission electron microscopy analyses confirm the reduction of magnetite to wüstite.
ISSN:2090-9063
2090-9071