{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI)
In the title complex, [U(C17H14BrN3O2S)O2(C2H5OH)], the UVI cation has a distorted pentagonal–bipyramidal environment with the pentagonal plane defined by two N and two O atoms of the tetradentate Schiff base ligand and the O atom of the ethanol molecule. Two oxide O atoms occupy the axial...
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International Union of Crystallography
2013-07-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813014669 |
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doaj-0bbf5d62901240f4939345f75a19c8402020-11-25T01:56:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697m362m36310.1107/S1600536813014669{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI)Roberto CentoreMehdi AhmadiAndrea PelusoIn the title complex, [U(C17H14BrN3O2S)O2(C2H5OH)], the UVI cation has a distorted pentagonal–bipyramidal environment with the pentagonal plane defined by two N and two O atoms of the tetradentate Schiff base ligand and the O atom of the ethanol molecule. Two oxide O atoms occupy the axial positions. The azomethine C=N group and the Br atom are disordered over two positions in a 0.8356 (18):0.1644 (18) ratio. The ethylthiolyl group is disordered over three conformations in a 0.8356 (18):0.085 (6):0.079 (6) ratio, and the ethanol ligand is also disordered over three orientations in a 0.470 (16):0.277 (19):0.253 (18) ratio. In the crystal, molecules form centrosymmetric dimers through hydrogen bonding between ethanol O—H donors and phenolate O-atom acceptors. Weak C—H...O interactions consolidate the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536813014669 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Roberto Centore Mehdi Ahmadi Andrea Peluso |
spellingShingle |
Roberto Centore Mehdi Ahmadi Andrea Peluso {4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI) Acta Crystallographica Section E |
author_facet |
Roberto Centore Mehdi Ahmadi Andrea Peluso |
author_sort |
Roberto Centore |
title |
{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI) |
title_short |
{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI) |
title_full |
{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI) |
title_fullStr |
{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI) |
title_full_unstemmed |
{4-Bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κO)amino-κN]methylidene}hydrazinylidene-κN1)methyl]phenolato-κO}(ethanol-κO)dioxidouranium(VI) |
title_sort |
{4-bromo-2-[(2-{(ethylsulfanyl)[(2-oxidobenzylidene-κo)amino-κn]methylidene}hydrazinylidene-κn1)methyl]phenolato-κo}(ethanol-κo)dioxidouranium(vi) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2013-07-01 |
description |
In the title complex, [U(C17H14BrN3O2S)O2(C2H5OH)], the UVI cation has a distorted pentagonal–bipyramidal environment with the pentagonal plane defined by two N and two O atoms of the tetradentate Schiff base ligand and the O atom of the ethanol molecule. Two oxide O atoms occupy the axial positions. The azomethine C=N group and the Br atom are disordered over two positions in a 0.8356 (18):0.1644 (18) ratio. The ethylthiolyl group is disordered over three conformations in a 0.8356 (18):0.085 (6):0.079 (6) ratio, and the ethanol ligand is also disordered over three orientations in a 0.470 (16):0.277 (19):0.253 (18) ratio. In the crystal, molecules form centrosymmetric dimers through hydrogen bonding between ethanol O—H donors and phenolate O-atom acceptors. Weak C—H...O interactions consolidate the crystal packing. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813014669 |
work_keys_str_mv |
AT robertocentore 4bromo22ethylsulfanyl2oxidobenzylidene954oamino954nmethylidenehydrazinylidene954n1methylphenolato954oethanol954odioxidouraniumvi AT mehdiahmadi 4bromo22ethylsulfanyl2oxidobenzylidene954oamino954nmethylidenehydrazinylidene954n1methylphenolato954oethanol954odioxidouraniumvi AT andreapeluso 4bromo22ethylsulfanyl2oxidobenzylidene954oamino954nmethylidenehydrazinylidene954n1methylphenolato954oethanol954odioxidouraniumvi |
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