Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efflorescence humidities

In order to study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour, we have employed a thermodynamic approach proposed by Shchekin et al. (2008). This approach uses the mechanic and thermodynamic concept of disjoining pressure of thin f...

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Bibliographic Details
Main Authors: O. Hellmuth, A. K. Shchekin
Format: Article
Language:English
Published: Copernicus Publications 2015-04-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/15/3851/2015/acp-15-3851-2015.pdf