H2O2 as green and environmentally benign reagent for the oxidation of TMS ethers, THP ethers, and alcohols in the presence of {[K.18-Crown-6]Br3}n

H2O2 as green and environmentally benign reagent for the oxidation of TMS ethers, THP ethers, and alcohols in the presence of {[K.18-Crown-6]Br3}n

In the presence of {[K.18-Crown-6]Br3}n, a unique tribromide reagent, trimethylsilyl (TMS) ethers, tetrahydropyranyl (THP) ethers, and alcohols were oxidized to their corresponding aldehydes and ketones in H2O2. One-pot deprotection and oxidation of TMS ethers/THP ethers were performed directly and...

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Bibliographic Details
Main Authors: Mohsen Rasouli, Mohammad Ali Zolfigol, Mohammad Hossein Moslemin, Gholamabbas Chehardoli
Format: Article
Language:English
Published: Taylor & Francis Group 2017-04-01
Series:Green Chemistry Letters and Reviews
Subjects:
H2O2
TMS ethers
THP ethers
{K.18-Crown-6]Br3}n
alcohols
Online Access:http://dx.doi.org/10.1080/17518253.2017.1306614

Internet

http://dx.doi.org/10.1080/17518253.2017.1306614

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