III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides
This paper is devoted to the bioconjugates of ferrocene with naturally occuring amino acids/peptides - mostly dealing with authors' results accompanied, to a lesser degree, by the relevant literature data. Chapter 2 deals with natural peptides and peptidomimetics...
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Online Access: | http://www.hdki.hr/kui/vol61/broj02/71.pdf |
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doaj-2378557af7a948ffbd47cd4cd358b6ef2020-11-24T22:47:30ZengCroatian Society of Chemical EngineersKemija u Industriji0022-98301334-90902012-02-01610271120III. Organometallic and Bioorganometallic Chemistry - Ferrocene PeptidesKovačević, M.Rapić, V.This paper is devoted to the bioconjugates of ferrocene with naturally occuring amino acids/peptides - mostly dealing with authors' results accompanied, to a lesser degree, by the relevant literature data. Chapter 2 deals with natural peptides and peptidomimetics, mainly focusing on α-helix and β pleated sheet (as the most important elements of peptide secondary and tertiary structure), and artificial β-sheets nucleated by non-amino acid turn inducers. Chapter 3 describes peptides generated from ferrocenecarboxylic acid and ferroceneamine, as well as with the bioconjugates of heteroannulary substituted ferrocene-1,1'-dicarboxylic acid (Fcd) and ferrocene-1,1'-diamine (Fcda). Chapter 4 elaborates authors' papers about peptides based on 1'-aminoferrocene-1-carboxylic acid (Fca). Chapter 5 is devoted to the new monosubstituted Fcd and Fcda conjugates with amino acids, while Chapter 6 describes our publications in the field of very topical peptidomimetics - ferrocene ureidopeptides and β peptides. Conformational analysis of the newly prepared ferrocene bioconjugates in solution and solid state was performed by means of spectroscopic methods (CD, IR, 1D- NMR, 2D-NMR, v. r. NMR, and temperature and concentration dependent NMR) and DFT calculations. http://www.hdki.hr/kui/vol61/broj02/71.pdfFerrocene Peptides |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kovačević, M. Rapić, V. |
spellingShingle |
Kovačević, M. Rapić, V. III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides Kemija u Industriji Ferrocene Peptides |
author_facet |
Kovačević, M. Rapić, V. |
author_sort |
Kovačević, M. |
title |
III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides |
title_short |
III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides |
title_full |
III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides |
title_fullStr |
III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides |
title_full_unstemmed |
III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides |
title_sort |
iii. organometallic and bioorganometallic chemistry - ferrocene peptides |
publisher |
Croatian Society of Chemical Engineers |
series |
Kemija u Industriji |
issn |
0022-9830 1334-9090 |
publishDate |
2012-02-01 |
description |
This paper is devoted to the bioconjugates of ferrocene with naturally occuring amino acids/peptides - mostly dealing with authors' results accompanied, to a lesser degree, by the relevant literature data. Chapter 2 deals with natural peptides and peptidomimetics, mainly focusing on α-helix and β pleated sheet (as the most important elements of peptide secondary and tertiary structure), and artificial β-sheets nucleated by non-amino acid turn inducers. Chapter 3 describes peptides generated from ferrocenecarboxylic acid and ferroceneamine, as well as with the bioconjugates of heteroannulary substituted ferrocene-1,1'-dicarboxylic acid (Fcd) and ferrocene-1,1'-diamine (Fcda). Chapter 4 elaborates authors' papers about peptides based on 1'-aminoferrocene-1-carboxylic acid (Fca). Chapter 5 is devoted to the new monosubstituted Fcd and Fcda conjugates with amino acids, while Chapter 6 describes our publications in the field of very topical peptidomimetics - ferrocene ureidopeptides and β peptides. Conformational analysis of the newly prepared ferrocene bioconjugates in solution and solid state was performed by means of spectroscopic methods (CD, IR, 1D- NMR, 2D-NMR, v. r. NMR, and temperature and concentration dependent NMR) and DFT calculations. |
topic |
Ferrocene Peptides |
url |
http://www.hdki.hr/kui/vol61/broj02/71.pdf |
work_keys_str_mv |
AT kovacevicm iiiorganometallicandbioorganometallicchemistryferrocenepeptides AT rapicv iiiorganometallicandbioorganometallicchemistryferrocenepeptides |
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1725681607440859136 |