Pentacarbonyl-1κ2C,2κ3C-[(diphenylphosphoryl)diphenylphosphane-1κP]-μ-ethane-1,2-dithiolato-1:2κ4S,S′:S,S′-diiron(I)(Fe—Fe)

The dinuclear title compound, [Fe2(C2H4S2)(C24H20OP2)(CO)5] or (μ-SCH2CH2S-μ)Fe2(CO)5[Ph2PP(O)Ph2], contains a butterfly-shaped Fe2S2 core in which the Fe...Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to th...

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Bibliographic Details
Main Authors: Xu-Feng Liu, Xiao-Yong Yu
Format: Article
Language:English
Published: International Union of Crystallography 2011-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811042139