Lewis Pair Catalysts in the Polymerization of Lactide and Related Cyclic Esters

Polyesters, especially poly(lactide) (PLA), are used widely as biodegradable and biocompatible materials, yet their controllable synthesis, especially the stereoselective synthesis of polyesters, is still a challenge. Recently some excellent Lewis pair catalysts for ring-opening polymerization (ROP)...

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Bibliographic Details
Main Authors: Xinlei Li, Changjuan Chen, Jincai Wu
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/23/1/189
Description
Summary:Polyesters, especially poly(lactide) (PLA), are used widely as biodegradable and biocompatible materials, yet their controllable synthesis, especially the stereoselective synthesis of polyesters, is still a challenge. Recently some excellent Lewis pair catalysts for ring-opening polymerization (ROP) of lactide and related cyclic esters have emerged. This review article will highlight the key advances in the ROP catalyzed by Lewis pair compounds with the aim of encouraging the wider application of Lewis pair catalysts in the polymerization of lactide and related cyclic esters.
ISSN:1420-3049