The crystal structure of the Dess–Martin periodinane

The crystal structure of the Dess–Martin periodinane

We report the elusive X-ray structure of the Dess–Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.

Bibliographic Details
Main Authors: Albert Schröckeneder, Desiree Stichnoth, Peter Mayer, Dirk Trauner
Format: Article
Language:English
Published: Beilstein-Institut 2012-09-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
crystal structure
Dess–Martin periodinane
halogen bonds
hypervalent iodine
oxidant
Online Access:https://doi.org/10.3762/bjoc.8.172

Internet

https://doi.org/10.3762/bjoc.8.172

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