DBFOX-Ph/metal complexes: Evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones

DBFOX-Ph/metal complexes: Evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones

We examined the catalytic enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones 1 with N-fluorobenzenesulfonimide (NFSI) by DBFOX-Ph/metal complexes under a variety of conditions. After optimization of the metal salts, solvents and additives, we found that the fluoro-2-thiazolidinones...

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Bibliographic Details
Main Authors: Takehisa Ishimaru, Norio Shibata, Dhande Sudhakar Reddy, Takao Horikawa, Shuichi Nakamura, Takeshi Toru
Format: Article
Language:English
Published: Beilstein-Institut 2008-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
fluorination
enantioselective
nickel
Lewis acid
catalyst
Online Access:https://doi.org/10.3762/bjoc.4.16

Internet

https://doi.org/10.3762/bjoc.4.16

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