N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate
In the title compound, C16H22N3OP·H2O, the P atom adopts a distorted tetrahedral environment with the bond angles around the P atom in the range 99.98 (7)–116.20 (7)°. The P—N bond length in the [(CH3)2N]P(O) fragment...
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International Union of Crystallography
2012-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812033995 |
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doaj-37d0354cf16f47ed8240ad3db4d2cd642020-11-24T21:31:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689o2650o265010.1107/S1600536812033995N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrateFarnaz EslamiMehrdad PourayoubiMohammad YousefiArnold L. RheingoldJames A. GolenIn the title compound, C16H22N3OP·H2O, the P atom adopts a distorted tetrahedral environment with the bond angles around the P atom in the range 99.98 (7)–116.20 (7)°. The P—N bond length in the [(CH3)2N]P(O) fragment [1.6392 (14) Å] is slightly shorter than two other P—N bonds [1.6439 (15) and 1.6530 (14) Å]. In the (CH3)2NP(O) fragment, one of the methyl groups is syn to the P=O bond, whereas the other one is anti to the P=O bond [C—N—P=O torsion angles = 4.80 (17) and −174.57 (15)°]. In the crystal, the water molecules form hydrogen bonds to the O atoms of the P=O bond of two different molecules and act as acceptors for the two amino H atoms of the same molecule. As a result, chains parallel to [010] are formed.http://scripts.iucr.org/cgi-bin/paper?S1600536812033995 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Farnaz Eslami Mehrdad Pourayoubi Mohammad Yousefi Arnold L. Rheingold James A. Golen |
spellingShingle |
Farnaz Eslami Mehrdad Pourayoubi Mohammad Yousefi Arnold L. Rheingold James A. Golen N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate Acta Crystallographica Section E |
author_facet |
Farnaz Eslami Mehrdad Pourayoubi Mohammad Yousefi Arnold L. Rheingold James A. Golen |
author_sort |
Farnaz Eslami |
title |
N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate |
title_short |
N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate |
title_full |
N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate |
title_fullStr |
N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate |
title_full_unstemmed |
N,N-Dimethyl-N′,N′′-bis(2-methylphenyl)phosphoric triamide monohydrate |
title_sort |
n,n-dimethyl-n′,n′′-bis(2-methylphenyl)phosphoric triamide monohydrate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-09-01 |
description |
In the title compound, C16H22N3OP·H2O, the P atom adopts a distorted tetrahedral environment with the bond angles around the P atom in the range 99.98 (7)–116.20 (7)°. The P—N bond length in the [(CH3)2N]P(O) fragment [1.6392 (14) Å] is slightly shorter than two other P—N bonds [1.6439 (15) and 1.6530 (14) Å]. In the (CH3)2NP(O) fragment, one of the methyl groups is syn to the P=O bond, whereas the other one is anti to the P=O bond [C—N—P=O torsion angles = 4.80 (17) and −174.57 (15)°]. In the crystal, the water molecules form hydrogen bonds to the O atoms of the P=O bond of two different molecules and act as acceptors for the two amino H atoms of the same molecule. As a result, chains parallel to [010] are formed. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812033995 |
work_keys_str_mv |
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