Extraordinarily large kinetic isotope effect on alkene hydrogenation over Rh-based intermetallic compounds

A series of Rh-based intermetallic compounds supported on silica was prepared and tested in alkene hydrogenation at room temperature. H2 and D2 were used as the hydrogen sources and the kinetic isotope effect (KIE) in hydrogenation was studied. In styrene hydrogenation, the KIE values differed stron...

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Bibliographic Details
Main Authors: Shinya Furukawa, Pingping Yi, Yuji Kunisada, Ken-Ichi Shimizu
Format: Article
Language:English
Published: Taylor & Francis Group 2019-12-01
Series:Science and Technology of Advanced Materials
Subjects:
Online Access:http://dx.doi.org/10.1080/14686996.2019.1642139