Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate

Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate

In the title hydrated molecular salt, [Mg(H2O)6](C13H9BrNO4S)2·2H2O, the Mg2+ ion (site symmetry overline{1}) adopts a near regular MgO6 octahedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intramolec...

Full description

Bibliographic Details
Main Author: Xi-Shi Tai
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810053717
id doaj-3bb6386b0414446fb0c5bdd16d31059b
record_format Article
spelling doaj-3bb6386b0414446fb0c5bdd16d31059b2020-11-24T22:09:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m132m13210.1107/S1600536810053717Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrateXi-Shi TaiIn the title hydrated molecular salt, [Mg(H2O)6](C13H9BrNO4S)2·2H2O, the Mg2+ ion (site symmetry overline{1}) adopts a near regular MgO6 octahedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intramolecular O—H...N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O—H...O and O—H...Br hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536810053717
collection DOAJ
language English
format Article
sources DOAJ
author Xi-Shi Tai
spellingShingle Xi-Shi Tai
Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
Acta Crystallographica Section E
author_facet Xi-Shi Tai
author_sort Xi-Shi Tai
title Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
title_short Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
title_full Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
title_fullStr Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
title_full_unstemmed Hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
title_sort hexaaquamagnesium bis{4-[(5-bromo-2-hydroxybenzylidene)amino]benzenesulfonate} dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-02-01
description In the title hydrated molecular salt, [Mg(H2O)6](C13H9BrNO4S)2·2H2O, the Mg2+ ion (site symmetry overline{1}) adopts a near regular MgO6 octahedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intramolecular O—H...N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O—H...O and O—H...Br hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810053717
work_keys_str_mv AT xishitai hexaaquamagnesiumbis45bromo2hydroxybenzylideneaminobenzenesulfonatedihydrate
_version_ 1725812101688066048

Similar Items