Synthesis of New Chiral Benzimidazolylidene–Rh Complexes and Their Application in Asymmetric Addition Reactions of Organoboronic Acids to Aldehydes
A series of novel chiral N-heterocyclic carbene rhodium complexes (NHC–Rh) based on benzimidazole have been prepared, and all of the NHC–Rh complexes were fully characterized by NMR and mass spectrometry. These complexes could be used as catalysts for the asymmetric 1,2-addition of organoboronic aci...
Main Authors: | Weiping He, Bihui Zhou, Jie Li, Jianyou Shi |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-09-01
|
Series: | Catalysts |
Subjects: | |
Online Access: | http://www.mdpi.com/2073-4344/6/9/132 |
Similar Items
-
Synthesis of C2-Symmetric Benzimidazolium Salts and Their Application in Palladium-Catalyzed Enantioselective Intramolecular α-Arylation of Amides
by: Weiping He, et al.
Published: (2016-06-01) -
Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters
by: Momoko Watanabe, et al.
Published: (2011-06-01) -
Biological Activities of NHC–Pd(II) Complexes Based on Benzimidazolylidene N-heterocyclic Carbene (NHC) Ligands Bearing Aryl Substituents
by: Ibrahim Al Nasr, et al.
Published: (2020-10-01) -
Asymmetric Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes Organocatalyzed by Chiral Monosalicylamides from trans-Cyclohexane-1,2-Diamines
by: José R. Martínez-Guillén, et al.
Published: (2018-01-01) -
Enantioselective Michael Addition of Aldehydes to Maleimides Organocatalyzed by a Chiral Primary Amine-Salicylamide
by: Alejandro Torregrosa-Chinillach, et al.
Published: (2018-12-01)