Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]

The title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. T...

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Main Authors: Hong-Yin He, Min-Min Li, Hai-Dong Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809012562
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spelling doaj-3eb8abbb46d148fd8bf1037e8de4ec122020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m510m51010.1107/S1600536809012562Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]Hong-Yin HeMin-Min LiHai-Dong WangThe title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitroisophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809012562
collection DOAJ
language English
format Article
sources DOAJ
author Hong-Yin He
Min-Min Li
Hai-Dong Wang
spellingShingle Hong-Yin He
Min-Min Li
Hai-Dong Wang
Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
Acta Crystallographica Section E
author_facet Hong-Yin He
Min-Min Li
Hai-Dong Wang
author_sort Hong-Yin He
title Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
title_short Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
title_full Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
title_fullStr Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
title_full_unstemmed Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
title_sort poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-05-01
description The title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitroisophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809012562
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AT minminli polydiamp9562acetatodiaquabis22amp8242bipyridinebisamp95635nitroisophthalatotricobaltii
AT haidongwang polydiamp9562acetatodiaquabis22amp8242bipyridinebisamp95635nitroisophthalatotricobaltii
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