Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]
The title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. T...
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International Union of Crystallography
2009-05-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809012562 |
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doaj-3eb8abbb46d148fd8bf1037e8de4ec122020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m510m51010.1107/S1600536809012562Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]Hong-Yin HeMin-Min LiHai-Dong WangThe title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitroisophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H...O hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809012562 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hong-Yin He Min-Min Li Hai-Dong Wang |
spellingShingle |
Hong-Yin He Min-Min Li Hai-Dong Wang Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)] Acta Crystallographica Section E |
author_facet |
Hong-Yin He Min-Min Li Hai-Dong Wang |
author_sort |
Hong-Yin He |
title |
Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)] |
title_short |
Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)] |
title_full |
Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)] |
title_fullStr |
Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)] |
title_full_unstemmed |
Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)] |
title_sort |
poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(ii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-05-01 |
description |
The title complex, [Co3(C8H3NO6)2(C2H3O2)2(C10H8N2)2(H2O)2], was synthesized under hydrothermal conditions. The structure features a centrosymmetric complex with three CoII centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octahedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitroisophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H...O hydrogen bonds. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809012562 |
work_keys_str_mv |
AT hongyinhe polydiamp9562acetatodiaquabis22amp8242bipyridinebisamp95635nitroisophthalatotricobaltii AT minminli polydiamp9562acetatodiaquabis22amp8242bipyridinebisamp95635nitroisophthalatotricobaltii AT haidongwang polydiamp9562acetatodiaquabis22amp8242bipyridinebisamp95635nitroisophthalatotricobaltii |
_version_ |
1725979951473098752 |