Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy

In this study, the effects of spinodal decomposition on the microstructures and mechanical properties of a TiZrNbTa alloy are investigated. The as-cast TiZrNbTa alloy possesses dual phases of TiZr-rich inter-dendrite (ID) and NbTa-rich dendrite (DR) domains, both of which have a body-centered cubic...

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Main Authors: Tai-You Liu, Jacob C. Huang, Wen-Shuo Chuang, Hung-Sheng Chou, Jui-Yu Wei, Chih-Yeh Chao, Yu-Chin Liao, Jason S.C. Jang
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/12/21/3508
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spelling doaj-482c08268df9417baa723fe429cab7252020-11-25T02:33:14ZengMDPI AGMaterials1996-19442019-10-011221350810.3390/ma12213508ma12213508Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy AlloyTai-You Liu0Jacob C. Huang1Wen-Shuo Chuang2Hung-Sheng Chou3Jui-Yu Wei4Chih-Yeh Chao5Yu-Chin Liao6Jason S.C. Jang7Department of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung 804, TaiwanDepartment of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung 804, TaiwanDepartment of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung 804, TaiwanDepartment of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung 804, TaiwanDepartment of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung 804, TaiwanDepartment of Mechanical Engineering, National Pingtung University of Science and Technology, Pingtung 912, TaiwanDepartment of Mechanical Engineering, National Central University, Taoyuan 320, TaiwanDepartment of Mechanical Engineering, National Central University, Taoyuan 320, TaiwanIn this study, the effects of spinodal decomposition on the microstructures and mechanical properties of a TiZrNbTa alloy are investigated. The as-cast TiZrNbTa alloy possesses dual phases of TiZr-rich inter-dendrite (ID) and NbTa-rich dendrite (DR) domains, both of which have a body-centered cubic (BCC) structure. In the DRs of the as-cast alloy, the α and ω precipitates are found to be uniformly distributed. After homogenization at 1100 °C for 24 h followed by water quenching, spinodal decomposition occurs and an interconnected structure with a wavelength of 20 nm is formed. The α and ω precipitates remained in the structure. Such a fine spinodal structure strengthens the alloy effectively. Detailed strengthening calculations were conducted in order to estimate the strengthening contributions from the α and ω precipitates, as well as the spinodal decomposition microstructure.https://www.mdpi.com/1996-1944/12/21/3508high entropy alloyspinodal decompositionstrengtheningprecipitate
collection DOAJ
language English
format Article
sources DOAJ
author Tai-You Liu
Jacob C. Huang
Wen-Shuo Chuang
Hung-Sheng Chou
Jui-Yu Wei
Chih-Yeh Chao
Yu-Chin Liao
Jason S.C. Jang
spellingShingle Tai-You Liu
Jacob C. Huang
Wen-Shuo Chuang
Hung-Sheng Chou
Jui-Yu Wei
Chih-Yeh Chao
Yu-Chin Liao
Jason S.C. Jang
Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy
Materials
high entropy alloy
spinodal decomposition
strengthening
precipitate
author_facet Tai-You Liu
Jacob C. Huang
Wen-Shuo Chuang
Hung-Sheng Chou
Jui-Yu Wei
Chih-Yeh Chao
Yu-Chin Liao
Jason S.C. Jang
author_sort Tai-You Liu
title Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy
title_short Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy
title_full Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy
title_fullStr Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy
title_full_unstemmed Spinodal Decomposition and Mechanical Response of a TiZrNbTa High-Entropy Alloy
title_sort spinodal decomposition and mechanical response of a tizrnbta high-entropy alloy
publisher MDPI AG
series Materials
issn 1996-1944
publishDate 2019-10-01
description In this study, the effects of spinodal decomposition on the microstructures and mechanical properties of a TiZrNbTa alloy are investigated. The as-cast TiZrNbTa alloy possesses dual phases of TiZr-rich inter-dendrite (ID) and NbTa-rich dendrite (DR) domains, both of which have a body-centered cubic (BCC) structure. In the DRs of the as-cast alloy, the α and ω precipitates are found to be uniformly distributed. After homogenization at 1100 °C for 24 h followed by water quenching, spinodal decomposition occurs and an interconnected structure with a wavelength of 20 nm is formed. The α and ω precipitates remained in the structure. Such a fine spinodal structure strengthens the alloy effectively. Detailed strengthening calculations were conducted in order to estimate the strengthening contributions from the α and ω precipitates, as well as the spinodal decomposition microstructure.
topic high entropy alloy
spinodal decomposition
strengthening
precipitate
url https://www.mdpi.com/1996-1944/12/21/3508
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