Hexaborate(2−) and Dodecaborate(6−) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{κ<sup>3</sup><i>O</i>-B<sub>6</sub>O<sub>7</sub>(OH)<sub>6</sub>}(κ<sup>3</sup><i>N</i>-dien)]·0.5H<sub>2</sub>O (dien = NH(CH<sub>2</sub>–CH<sub>2</sub>NH<sub>2</sub>)<sub>2</sub>), (NH<sub>4</sub>)<sub>2</sub>[Zn{κ<sup>2</sup><i>O</i>-B<sub>6</sub>O<sub>7</sub>(OH)<sub>6</sub>}<sub>2</sub> (H<sub>2</sub>O)<sub>2</sub>]·2H<sub>2</sub>O and (1,3-pnH<sub>2</sub>)<sub>3</sub>[(κ<sup>1</sup><i>N</i>-H<sub>3</sub>N{CH<sub>2</sub>}<sub>3</sub>NH<sub>2</sub>) Zn{κ<sup>3</sup><i>O</i>-B<sub>12</sub>O<sub>18</sub>(OH)<sub>6</sub>}]<sub>2</sub>·14H<sub>2</sub>O (1,3-pn = 1,3-diaminopropane)
Two zinc(II) hexaborate(2−) complexes, [Zn{κ<sup>3</sup><i>O</i>-B<sub>6</sub>O<sub>7</sub>(OH)<sub>6</sub>}(κ<sup>3</sup><i>N</i>-dien)]·0.5H<sub>2</sub>O (dien = NH(...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-03-01
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| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/7/4/44 |