Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal
Methane is the main component of natural gas and this research provides the platrorm on the potential of utilizing natural gas, found abundant in Indonesia, to form gasoline. The objectives of the research are to modify HZSM-5 zeolite with a series of transition metals (Cr, Mn, Co, Ni, Cu, and Pt) a...
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2017-06-01
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doaj-500af32b9ff140b2a64ab907e3b2489f2020-11-24T21:17:12ZengDiponegoro UniversityReaktor0852-07982407-59732017-06-017171310.14710/reaktor.7.1.7-1311408Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With MetalD. D. AnggoroMethane is the main component of natural gas and this research provides the platrorm on the potential of utilizing natural gas, found abundant in Indonesia, to form gasoline. The objectives of the research are to modify HZSM-5 zeolite with a series of transition metals (Cr, Mn, Co, Ni, Cu, and Pt) and Ga , and to evaluate the performances of these catalyst for the single step conversion of methane to gasoline. The oxidation of methane were carried out in a micro-packed bed reactor at atmoepheric pressure, temperature 800 0C, F/W = 10440 ml/g.hr and 9%vol O2. Metals were loaded into the HZSM-5 zeolite by the wetness incipient impregnation method. The characterization results indicated that the ionic metals (Mn+) occupy the H+ position of HZSM-5 and metal loaded HZSM-5. Ni- HZSM-5, Cu- HZSM-5 and Ga- HZSM-5 gave a high methane conversion and high gasoline selectivity. Among the catalyst samles tested, Cr- HZSM-5 showed the highest Research Octane Number (RON=86). These catalyst have the potential to convert natural gas to C5+ liquid hydrocarbons provided the oxidation, dehydration and oligomerization function of the metals are in balance. Keywords : direct conversion, methane, liquid hydrocarbons, metal, HZSM-5https://ejournal.undip.ac.id/index.php/reaktor/article/view/14994direct conversion, methane, liquid hydrocarbons, metal, HZSM-5 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
D. D. Anggoro |
spellingShingle |
D. D. Anggoro Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal Reaktor direct conversion, methane, liquid hydrocarbons, metal, HZSM-5 |
author_facet |
D. D. Anggoro |
author_sort |
D. D. Anggoro |
title |
Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal |
title_short |
Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal |
title_full |
Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal |
title_fullStr |
Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal |
title_full_unstemmed |
Direct Convertion Of Methane To Liquid Hydrocarbons Using HZSM-5 Zeolite Catalyst Loaded With Metal |
title_sort |
direct convertion of methane to liquid hydrocarbons using hzsm-5 zeolite catalyst loaded with metal |
publisher |
Diponegoro University |
series |
Reaktor |
issn |
0852-0798 2407-5973 |
publishDate |
2017-06-01 |
description |
Methane is the main component of natural gas and this research provides the platrorm on the potential of utilizing natural gas, found abundant in Indonesia, to form gasoline. The objectives of the research are to modify HZSM-5 zeolite with a series of transition metals (Cr, Mn, Co, Ni, Cu, and Pt) and Ga , and to evaluate the performances of these catalyst for the single step conversion of methane to gasoline. The oxidation of methane were carried out in a micro-packed bed reactor at atmoepheric pressure, temperature 800 0C, F/W = 10440 ml/g.hr and 9%vol O2. Metals were loaded into the HZSM-5 zeolite by the wetness incipient impregnation method. The characterization results indicated that the ionic metals (Mn+) occupy the H+ position of HZSM-5 and metal loaded HZSM-5. Ni- HZSM-5, Cu- HZSM-5 and Ga- HZSM-5 gave a high methane conversion and high gasoline selectivity. Among the catalyst samles tested, Cr- HZSM-5 showed the highest Research Octane Number (RON=86). These catalyst have the potential to convert natural gas to C5+ liquid hydrocarbons provided the oxidation, dehydration and oligomerization function of the metals are in balance.
Keywords : direct conversion, methane, liquid hydrocarbons, metal, HZSM-5 |
topic |
direct conversion, methane, liquid hydrocarbons, metal, HZSM-5 |
url |
https://ejournal.undip.ac.id/index.php/reaktor/article/view/14994 |
work_keys_str_mv |
AT ddanggoro directconvertionofmethanetoliquidhydrocarbonsusinghzsm5zeolitecatalystloadedwithmetal |
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1726013633642627072 |