Influence of 1 and 5 wt% TiC additions on the oxidation behaviour of pure tungsten

The influence of 1 and 5 wt% of TiC nanoparticles on the oxidation behaviour of reinforced tungsten has been evaluated up to 700 °C in dry air. Isothermal thermogravimetric tests prove that the addition of 5 wt% of TiC particles is detrimental, increasing the mass gain of pure tungsten by a factor o...

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Bibliographic Details
Main Authors: Pablo Pérez, Miguel A. Monge, Ángel Muñoz, Paloma Adeva
Format: Article
Language:English
Published: Elsevier 2020-08-01
Series:Nuclear Materials and Energy
Subjects:
TiC
Online Access:http://www.sciencedirect.com/science/article/pii/S2352179120300569
Description
Summary:The influence of 1 and 5 wt% of TiC nanoparticles on the oxidation behaviour of reinforced tungsten has been evaluated up to 700 °C in dry air. Isothermal thermogravimetric tests prove that the addition of 5 wt% of TiC particles is detrimental, increasing the mass gain of pure tungsten by a factor of ten. TiC particles act as stress concentrators, facilitating microcracking events within the scale and promoting decohesion between TiC-free boundaries and TiC-containing regions of the material. Compared to pure tungsten, lowering TiC addition to 1 wt% significantly improves the oxidation resistance at 700 °C by reducing about seven times the mass gain, while at 600 °C both materials exhibit similar resistance. At 700 °C, the presence of 1 wt% of TiC particles inhibits massive microcracking events occurring in the scale formed on pure tungsten, rendering the oxide scale denser and more protective.
ISSN:2352-1791