The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines

Background<p>Chiral base desymmetrisation of dimethyl sulfoximines could provide a general route to chiral, enantioenriched dialkyl sulfoximines with potential for use in asymmetric catalysis.</p><p>Results</p><p>Asymmetric deprotonation of N-trialkylsilyl dimethyl sulf...

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Bibliographic Details
Main Authors: Matthew J. McGrath, Carsten Bolm
Format: Article
Language:English
Published: Beilstein-Institut 2007-10-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-3-33