Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water

Co-Ni catalysts, prepared by a typical wetness impregnation method, can selectively convert furfural (FFA) to cyclopentanone (CPO) or cyclopentanol (CPL) in water, respectively. The catalytic performance depends strongly on the support. It is also strongly influenced by the Co-Ni loadings of the cat...

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Main Authors:	Yaru Li, Xingcui Guo, Daosheng Liu, Xindong Mu, Xiufang Chen, Yan Shi
Format:	Article
Language:	English
Published:	MDPI AG 2018-05-01
Series:	Catalysts
Subjects:	furfural Co-Ni catalyst cyclopentanone cyclopentanol hydrogenation
Online Access:	http://www.mdpi.com/2073-4344/8/5/193

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spelling	doaj-6f8d81e8e0254b5883e546b5416d6d612020-11-24T22:55:06ZengMDPI AGCatalysts2073-43442018-05-018519310.3390/catal8050193catal8050193Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in WaterYaru Li0Xingcui Guo1Daosheng Liu2Xindong Mu3Xiufang Chen4Yan Shi5College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, 1 Dandong Road, Fushun, Liaoning 113001, ChinaCAS Key Laboratory of Bio-Based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, ChinaCollege of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, 1 Dandong Road, Fushun, Liaoning 113001, ChinaCAS Key Laboratory of Bio-Based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, ChinaCAS Key Laboratory of Bio-Based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, ChinaCollege of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, 1 Dandong Road, Fushun, Liaoning 113001, ChinaCo-Ni catalysts, prepared by a typical wetness impregnation method, can selectively convert furfural (FFA) to cyclopentanone (CPO) or cyclopentanol (CPL) in water, respectively. The catalytic performance depends strongly on the support. It is also strongly influenced by the Co-Ni loadings of the catalyst. The 10%Co-10%Ni/TiO2 catalyst showed the highest selectivity toward CPO (53.3%) with almost complete FFA conversion, and the main product was CPL (45.4%) over 20%Co/TiO2 at the optimized conditions (150 °C, 4 MPa H2, 4 h). The surface morphology, surface area, composition and reducibility properties of these catalysts were fully characterized by XRD, H2-TPR, ICP-AES and SEM. The factors that influenced the activity of catalysts were also investigated in detail. Additionally, the stability of catalyst for the hydrogenative rearrangement of FFA was studied.http://www.mdpi.com/2073-4344/8/5/193furfuralCo-Ni catalystcyclopentanonecyclopentanolhydrogenation
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Yaru Li Xingcui Guo Daosheng Liu Xindong Mu Xiufang Chen Yan Shi
spellingShingle	Yaru Li Xingcui Guo Daosheng Liu Xindong Mu Xiufang Chen Yan Shi Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water Catalysts furfural Co-Ni catalyst cyclopentanone cyclopentanol hydrogenation
author_facet	Yaru Li Xingcui Guo Daosheng Liu Xindong Mu Xiufang Chen Yan Shi
author_sort	Yaru Li
title	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
title_short	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
title_full	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
title_fullStr	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
title_full_unstemmed	Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
title_sort	selective conversion of furfural to cyclopentanone or cyclopentanol using co-ni catalyst in water
publisher	MDPI AG
series	Catalysts
issn	2073-4344
publishDate	2018-05-01
description	Co-Ni catalysts, prepared by a typical wetness impregnation method, can selectively convert furfural (FFA) to cyclopentanone (CPO) or cyclopentanol (CPL) in water, respectively. The catalytic performance depends strongly on the support. It is also strongly influenced by the Co-Ni loadings of the catalyst. The 10%Co-10%Ni/TiO2 catalyst showed the highest selectivity toward CPO (53.3%) with almost complete FFA conversion, and the main product was CPL (45.4%) over 20%Co/TiO2 at the optimized conditions (150 °C, 4 MPa H2, 4 h). The surface morphology, surface area, composition and reducibility properties of these catalysts were fully characterized by XRD, H2-TPR, ICP-AES and SEM. The factors that influenced the activity of catalysts were also investigated in detail. Additionally, the stability of catalyst for the hydrogenative rearrangement of FFA was studied.
topic	furfural Co-Ni catalyst cyclopentanone cyclopentanol hydrogenation
url	http://www.mdpi.com/2073-4344/8/5/193
work_keys_str_mv	AT yaruli selectiveconversionoffurfuraltocyclopentanoneorcyclopentanolusingconicatalystinwater AT xingcuiguo selectiveconversionoffurfuraltocyclopentanoneorcyclopentanolusingconicatalystinwater AT daoshengliu selectiveconversionoffurfuraltocyclopentanoneorcyclopentanolusingconicatalystinwater AT xindongmu selectiveconversionoffurfuraltocyclopentanoneorcyclopentanolusingconicatalystinwater AT xiufangchen selectiveconversionoffurfuraltocyclopentanoneorcyclopentanolusingconicatalystinwater AT yanshi selectiveconversionoffurfuraltocyclopentanoneorcyclopentanolusingconicatalystinwater
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Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water

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