Synthesis and selected transformations of 2-unsubstituted 1-(adamantyloxy)imidazole 3-oxides: straightforward access to non-symmetric 1,3-dialkoxyimidazolium salts

Synthesis and selected transformations of 2-unsubstituted 1-(adamantyloxy)imidazole 3-oxides: straightforward access to non-symmetric 1,3-dialkoxyimidazolium salts

Adamantyloxyamine reacts with formaldehyde to give N-(adamantyloxy)formaldimine as a room-temperature-stable compound that exists in solution in monomeric form. This product was used for reactions with α-hydroxyiminoketones leading to a new class of 2-unsubstituted imidazole 3-oxides bearing the ada...

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Bibliographic Details
Main Authors: Grzegorz Mlostoń, Małgorzata Celeda, Katarzyna Urbaniak, Marcin Jasiński, Vladyslav Bakhonsky, Peter R. Schreiner, Heinz Heimgartner
Format: Article
Language:English
Published: Beilstein-Institut 2019-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
alkoxyamines
imidazole N-oxides
imidazolium salts
nucleophilic carbenes
sulfur transfer reaction
Online Access:https://doi.org/10.3762/bjoc.15.43

Internet

https://doi.org/10.3762/bjoc.15.43

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