Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster
This paper reports on the synthesis of a new trinuclear homometalic mixed-valent iron carboxylate cluster with furan-2-carboxylic acid. The complex with the formula [Fe2IIIFeIIO(C4H3OCOO)6(H2O)3]∙0.5CH3CN•2.25H2O was characterized by X-ray analysis that revealed that the compound crystalizes in the...
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Academy of Sciences of Moldova, Institute of Chemistry
2018-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
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http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.504-Cuzan.pdf
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doaj-9b256f507f274a13abf0d429af5d24c82021-07-02T07:14:28ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882018-12-01132485510.19261/cjm.2018.504504Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron ClusterOlesea Cuzan-Munteanu0Silvia Melnic1Sergiu Shova2 Institute of Chemistry, 3, Academiei str., Chisinau MD 2028, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD 2028, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD 2028, Republic of Moldova This paper reports on the synthesis of a new trinuclear homometalic mixed-valent iron carboxylate cluster with furan-2-carboxylic acid. The complex with the formula [Fe2IIIFeIIO(C4H3OCOO)6(H2O)3]∙0.5CH3CN•2.25H2O was characterized by X-ray analysis that revealed that the compound crystalizes in the triclinic centrosymmetric group P-1, with the following unit cell parameters: a = 10.2758(6)Å, b = 11.5991(9) Å, c = 19.7349(15) Å, α = 105.060(7)°, β = 94.216(6)°, γ = 101.662(6)°. http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.504-Cuzan.pdf iron clustermixed valenceX-ray analysisµ3-oxocrystal structurehydrogen bond |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Olesea Cuzan-Munteanu Silvia Melnic Sergiu Shova |
| spellingShingle |
Olesea Cuzan-Munteanu Silvia Melnic Sergiu Shova Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry iron cluster mixed valence X-ray analysis µ3-oxo crystal structure hydrogen bond |
| author_facet |
Olesea Cuzan-Munteanu Silvia Melnic Sergiu Shova |
| author_sort |
Olesea Cuzan-Munteanu |
| title |
Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster |
| title_short |
Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster |
| title_full |
Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster |
| title_fullStr |
Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster |
| title_full_unstemmed |
Synthesis and X-ray Characterisation of a New Mixed-valence Trinuclear Iron Cluster |
| title_sort |
synthesis and x-ray characterisation of a new mixed-valence trinuclear iron cluster |
| publisher |
Academy of Sciences of Moldova, Institute of Chemistry |
| series |
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| issn |
1857-1727 2345-1688 |
| publishDate |
2018-12-01 |
| description |
This paper reports on the synthesis of a new trinuclear homometalic mixed-valent iron carboxylate cluster with furan-2-carboxylic acid. The complex with the formula [Fe2IIIFeIIO(C4H3OCOO)6(H2O)3]∙0.5CH3CN•2.25H2O was characterized by X-ray analysis that revealed that the compound crystalizes in the triclinic centrosymmetric group P-1, with the following unit cell parameters: a = 10.2758(6)Å, b = 11.5991(9) Å, c = 19.7349(15) Å, α = 105.060(7)°, β = 94.216(6)°, γ = 101.662(6)°. |
| topic |
iron cluster mixed valence X-ray analysis µ3-oxo crystal structure hydrogen bond |
| url |
http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2018.504-Cuzan.pdf
|
| work_keys_str_mv |
AT oleseacuzanmunteanu synthesisandxraycharacterisationofanewmixedvalencetrinuclearironcluster AT silviamelnic synthesisandxraycharacterisationofanewmixedvalencetrinuclearironcluster AT sergiushova synthesisandxraycharacterisationofanewmixedvalencetrinuclearironcluster |
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1721336386423881728 |