Catalytic Pyrolysis of Aliphatic Carboxylic Acids into Symmetric Ketones over Ceria-Based Catalysts: Kinetics, Isotope Effect and Mechanism

Catalytic Pyrolysis of Aliphatic Carboxylic Acids into Symmetric Ketones over Ceria-Based Catalysts: Kinetics, Isotope Effect and Mechanism

Ketonization is a promising way for upgrading bio-derived carboxylic acids from pyrolysis bio-oils, waste oils, and fats to produce high value-added chemicals and biofuels. Therefore, an understanding of its mechanism can help to carry out the catalytic pyrolysis of biomass more efficiently. Here we...

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Bibliographic Details
Main Authors: Tetiana Kulik, Borys Palianytsia, Mats Larsson
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Catalysts
Subjects:
carboxylic acids upgrading
ketonization
deuterated acetic acid
acetone d-isotopomers distribution
h/d exchange
inverse deuterium kinetic isotope effect
kinetic parameters
activation energy
catalytic pyrolysis of biomass
bio-oil
Online Access:https://www.mdpi.com/2073-4344/10/2/179

Internet

https://www.mdpi.com/2073-4344/10/2/179

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