{5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate

{5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate

The tetradentate dianion in the title complex hydrate, [Cu(C23H28N2O4)]·H2O, provides the CuII atom with a cis-N2O2 donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC3N chelate rings being 32.14&...

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Main Authors: Edward R. T. Tiekink, Seik Weng Ng, Ehsan Elahi, Saeed Rayati, Akbar Ghaemi
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681103889X
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spelling doaj-a260d18ef5da48958f3a8261c5a266322020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1445m144610.1107/S160053681103889X{5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrateEdward R. T. TiekinkSeik Weng NgEhsan ElahiSaeed RayatiAkbar GhaemiThe tetradentate dianion in the title complex hydrate, [Cu(C23H28N2O4)]·H2O, provides the CuII atom with a cis-N2O2 donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC3N chelate rings being 32.14 (8)°. The water molecule forms hydrogen bonds to each of the coordinating O atoms of a given complex molecule. Supramolecular layers in the bc plane are formed in the crystal packing through C—H...O and C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S160053681103889X
collection DOAJ
language English
format Article
sources DOAJ
author Edward R. T. Tiekink
Seik Weng Ng
Ehsan Elahi
Saeed Rayati
Akbar Ghaemi
spellingShingle Edward R. T. Tiekink
Seik Weng Ng
Ehsan Elahi
Saeed Rayati
Akbar Ghaemi
{5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
Acta Crystallographica Section E
author_facet Edward R. T. Tiekink
Seik Weng Ng
Ehsan Elahi
Saeed Rayati
Akbar Ghaemi
author_sort Edward R. T. Tiekink
title {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
title_short {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
title_full {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
title_fullStr {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
title_full_unstemmed {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4O,N,N′,O′}copper(II) monohydrate
title_sort {5,5′-dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ4o,n,n′,o′}copper(ii) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description The tetradentate dianion in the title complex hydrate, [Cu(C23H28N2O4)]·H2O, provides the CuII atom with a cis-N2O2 donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC3N chelate rings being 32.14 (8)°. The water molecule forms hydrogen bonds to each of the coordinating O atoms of a given complex molecule. Supramolecular layers in the bc plane are formed in the crystal packing through C—H...O and C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S160053681103889X
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AT seikwengng 55amp8242dimethoxy22amp824211amp824222dimethylpropane13diyldinitrilodiethylidynediphenolatoamp9544onnamp8242oamp8242copperiimonohydrate
AT ehsanelahi 55amp8242dimethoxy22amp824211amp824222dimethylpropane13diyldinitrilodiethylidynediphenolatoamp9544onnamp8242oamp8242copperiimonohydrate
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