Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry

Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry

The high energy packed in alkyne functional group makes alkyne reactions highly thermodynamically favorable and generally irreversible. Furthermore, the presence of two orthogonal π-bonds that can be manipulated separately enables flexible synthetic cascades stemming from alkynes. Behind thes...

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Bibliographic Details
Main Authors: Igor V. Alabugin, Edgar Gonzalez-Rodriguez, Rahul Kisan Kawade, Aleksandr A. Stepanov, Sergei F. Vasilevsky
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Molecules
Subjects:
alkynes
carbonyl compounds
ketones
aldehydes
condensations
cyclizations
catalysis
nucleophilic addition
acetals
rearrangements
electronic structure
Online Access:http://www.mdpi.com/1420-3049/24/6/1036

Internet

http://www.mdpi.com/1420-3049/24/6/1036

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