Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate

Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate

In the title compound, [Ag{P(C6H11)2(C6H5)}2]ClO4·CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag&am...

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Main Authors: Apollinaire Munyaneza, Reinout Meijboom, Bernard Omondi
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811009822
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spelling doaj-ad937411e8c141029080d987950b4c3a2020-11-25T01:21:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m483m48410.1107/S1600536811009822Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvateApollinaire MunyanezaReinout MeijboomBernard OmondiIn the title compound, [Ag{P(C6H11)2(C6H5)}2]ClO4·CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag...Operchlorate interaction of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the AgI atom. Weak intermolecular C—H...O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536811009822
collection DOAJ
language English
format Article
sources DOAJ
author Apollinaire Munyaneza
Reinout Meijboom
Bernard Omondi
spellingShingle Apollinaire Munyaneza
Reinout Meijboom
Bernard Omondi
Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
Acta Crystallographica Section E
author_facet Apollinaire Munyaneza
Reinout Meijboom
Bernard Omondi
author_sort Apollinaire Munyaneza
title Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
title_short Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
title_full Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
title_fullStr Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
title_full_unstemmed Bis[dicyclohexyl(phenyl)phosphane-κP]silver(I) perchlorate dichloromethane monosolvate
title_sort bis[dicyclohexyl(phenyl)phosphane-κp]silver(i) perchlorate dichloromethane monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-04-01
description In the title compound, [Ag{P(C6H11)2(C6H5)}2]ClO4·CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag—P = 2.3993 (4) and 2.4011 (4) Å; P—Ag—P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag...Operchlorate interaction of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the AgI atom. Weak intermolecular C—H...O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811009822
work_keys_str_mv AT apollinairemunyaneza bisdicyclohexylphenylphosphaneamp954psilveriperchloratedichloromethanemonosolvate
AT reinoutmeijboom bisdicyclohexylphenylphosphaneamp954psilveriperchloratedichloromethanemonosolvate
AT bernardomondi bisdicyclohexylphenylphosphaneamp954psilveriperchloratedichloromethanemonosolvate
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