Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device
To achieve an efficient hole injection into triphenylamine derivatives cast on an Au electrode, we focused on the use of Fullerene (C60)-doped triphenylamine derivative as a buffer layer. After measuring the current-voltage properties of a layered device with the Au/C60-doped triphenylamine derivati...
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The Electrochemical Society of Japan
2020-09-01
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doaj-b538bb35857a4382b0916789b6cb7e552021-09-02T08:46:40ZengThe Electrochemical Society of JapanElectrochemistry2186-24512020-09-0188535035210.5796/electrochemistry.20-64056electrochemistryRectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer DeviceShofu MATSUDA0Chikara ITAGAKI1Masamichi ITO2Minoru UMEDA3Department of Materials Science and Technology, Faculty of Engineering, Nagaoka University of TechnologyDepartment of Materials Science and Technology, Faculty of Engineering, Nagaoka University of TechnologyDepartment of Materials Science and Technology, Faculty of Engineering, Nagaoka University of TechnologyDepartment of Materials Science and Technology, Faculty of Engineering, Nagaoka University of TechnologyTo achieve an efficient hole injection into triphenylamine derivatives cast on an Au electrode, we focused on the use of Fullerene (C60)-doped triphenylamine derivative as a buffer layer. After measuring the current-voltage properties of a layered device with the Au/C60-doped triphenylamine derivative/triphenylamine derivative/Au, hole injection was improved only at the interface where C60 was introduced. In addition, when 1 mol% of C60 was doped, the energy barrier for the hole injection decreased to 0.06 eV from 0.43 eV. Overall, we successfully developed a device with enhanced rectification properties.https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64056/_pdf/-char/enfullerenetriphenylamine derivativehole injectionrectification |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shofu MATSUDA Chikara ITAGAKI Masamichi ITO Minoru UMEDA |
spellingShingle |
Shofu MATSUDA Chikara ITAGAKI Masamichi ITO Minoru UMEDA Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device Electrochemistry fullerene triphenylamine derivative hole injection rectification |
author_facet |
Shofu MATSUDA Chikara ITAGAKI Masamichi ITO Minoru UMEDA |
author_sort |
Shofu MATSUDA |
title |
Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device |
title_short |
Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device |
title_full |
Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device |
title_fullStr |
Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device |
title_full_unstemmed |
Rectification Characteristics of C60-doped 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine Dual-layer Device |
title_sort |
rectification characteristics of c60-doped 4-(2,2-diphenylethenyl)-n,n-bis(4-methylphenyl)-benzenamine dual-layer device |
publisher |
The Electrochemical Society of Japan |
series |
Electrochemistry |
issn |
2186-2451 |
publishDate |
2020-09-01 |
description |
To achieve an efficient hole injection into triphenylamine derivatives cast on an Au electrode, we focused on the use of Fullerene (C60)-doped triphenylamine derivative as a buffer layer. After measuring the current-voltage properties of a layered device with the Au/C60-doped triphenylamine derivative/triphenylamine derivative/Au, hole injection was improved only at the interface where C60 was introduced. In addition, when 1 mol% of C60 was doped, the energy barrier for the hole injection decreased to 0.06 eV from 0.43 eV. Overall, we successfully developed a device with enhanced rectification properties. |
topic |
fullerene triphenylamine derivative hole injection rectification |
url |
https://www.jstage.jst.go.jp/article/electrochemistry/88/5/88_20-64056/_pdf/-char/en |
work_keys_str_mv |
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_version_ |
1721177558253305856 |