1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene

1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene

The title centrosymmetric molecule, C46H42Si2, is composed of a central benzene ring with buta-1,3-diynyl chains at positions 1 and 4. These chains are terminated by tert-butyldiphenylsilyl groups, hence the molecule is dumbbell in shape. The molecules are connected via C—H...&...

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Main Authors: Damien Thevenet, Reinhard Neier, Helen Stoeckli-Evans
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681000351X
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spelling doaj-b9fc9208c3004c2aaa8872ded8d0956f2020-11-25T01:15:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664o839o84010.1107/S160053681000351X1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzeneDamien ThevenetReinhard NeierHelen Stoeckli-EvansThe title centrosymmetric molecule, C46H42Si2, is composed of a central benzene ring with buta-1,3-diynyl chains at positions 1 and 4. These chains are terminated by tert-butyldiphenylsilyl groups, hence the molecule is dumbbell in shape. The molecules are connected via C—H...π interactions in the structure, so forming an undulating two-dimensional network in the bc plane. There is also a weak π–π interaction involving centrosymmetrically related phenyl rings with a centroid–centroid distance of 3.8359 (11) Å. http://scripts.iucr.org/cgi-bin/paper?S160053681000351X
collection DOAJ
language English
format Article
sources DOAJ
author Damien Thevenet
Reinhard Neier
Helen Stoeckli-Evans
spellingShingle Damien Thevenet
Reinhard Neier
Helen Stoeckli-Evans
1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
Acta Crystallographica Section E
author_facet Damien Thevenet
Reinhard Neier
Helen Stoeckli-Evans
author_sort Damien Thevenet
title 1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
title_short 1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
title_full 1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
title_fullStr 1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
title_full_unstemmed 1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
title_sort 1,4-bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description The title centrosymmetric molecule, C46H42Si2, is composed of a central benzene ring with buta-1,3-diynyl chains at positions 1 and 4. These chains are terminated by tert-butyldiphenylsilyl groups, hence the molecule is dumbbell in shape. The molecules are connected via C—H...π interactions in the structure, so forming an undulating two-dimensional network in the bc plane. There is also a weak π–π interaction involving centrosymmetrically related phenyl rings with a centroid–centroid distance of 3.8359 (11) Å.
url http://scripts.iucr.org/cgi-bin/paper?S160053681000351X
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AT reinhardneier 14bis4tertbutyldiphenylsilylbuta13diynylbenzene
AT helenstoecklievans 14bis4tertbutyldiphenylsilylbuta13diynylbenzene
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