The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites

This study was conducted to determine the influence of the oil palm boiler ash (OPBA) reinforcement on the microstructural, physical, mechanical and thermal properties of epoxy polymer composites. The chemical composition analysis of OPBA revealed that it contains about 55 wt.% of SiO2 along with ot...

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Main Authors: Samsul Rizal, H.M. Fizree, Md. Sohrab Hossain, Ikramullah, Deepu A. Gopakumar, Eunice Chong Wan Ni, H.P.S. Abdul Khalil
Format: Article
Language:English
Published: Elsevier 2020-03-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844020303959
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spelling doaj-c516619729b944b2bd18ad3ca53df3052020-11-25T02:00:29ZengElsevierHeliyon2405-84402020-03-0163e03550The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer compositesSamsul Rizal0H.M. Fizree1Md. Sohrab Hossain2 Ikramullah3Deepu A. Gopakumar4Eunice Chong Wan Ni5H.P.S. Abdul Khalil6Department of Mechanical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia; Corresponding author.School of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, MalaysiaSchool of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, Malaysia; Corresponding author.Department of Mechanical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, IndonesiaSchool of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, MalaysiaSchool of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, MalaysiaSchool of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, Malaysia; Corresponding author.This study was conducted to determine the influence of the oil palm boiler ash (OPBA) reinforcement on the microstructural, physical, mechanical and thermal properties of epoxy polymer composites. The chemical composition analysis of OPBA revealed that it contains about 55 wt.% of SiO2 along with other metallic oxides and elements. The surface morphology of OPBA showed angular and irregular shapes with porous structures. The influence of OPBA as a reinforcement in epoxy composite was studied with varying filler loadings (10–50 wt.%) and different particle sizes (50–150 μm). The result showed that the incorporation of OPBA in composites has improved the physical, mechanical and thermal properties of the epoxy matrix. The highest physical and mechanical properties of fabricated composites were attained with 30 wt.% loading and size of 50 μm. Also, thermal stability and the percentage of char residue of the composite increased with increasing filler loading. Furthermore, the contact angle of OPBA reinforced epoxy composites increased with the increase of filler loading. The lowest value of the contact angle was obtained at 30 wt.% of filler loading with the OPBA particle size of 50 μm. The finding of this study reveals that the OPBA has the potential to be used as reinforcement or filler as well as an alternative of silica-based inorganic fillers used in the enhancement of mechanical, physical and thermal properties of the epoxy polymer composite.http://www.sciencedirect.com/science/article/pii/S2405844020303959Materials scienceAgro-industrial wasteInorganic SiO2Oil palm boiler ashMicro fillerEpoxy composites
collection DOAJ
language English
format Article
sources DOAJ
author Samsul Rizal
H.M. Fizree
Md. Sohrab Hossain
Ikramullah
Deepu A. Gopakumar
Eunice Chong Wan Ni
H.P.S. Abdul Khalil
spellingShingle Samsul Rizal
H.M. Fizree
Md. Sohrab Hossain
Ikramullah
Deepu A. Gopakumar
Eunice Chong Wan Ni
H.P.S. Abdul Khalil
The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
Heliyon
Materials science
Agro-industrial waste
Inorganic SiO2
Oil palm boiler ash
Micro filler
Epoxy composites
author_facet Samsul Rizal
H.M. Fizree
Md. Sohrab Hossain
Ikramullah
Deepu A. Gopakumar
Eunice Chong Wan Ni
H.P.S. Abdul Khalil
author_sort Samsul Rizal
title The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
title_short The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
title_full The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
title_fullStr The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
title_full_unstemmed The role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
title_sort role of silica-containing agro-industrial waste as reinforcement on physicochemical and thermal properties of polymer composites
publisher Elsevier
series Heliyon
issn 2405-8440
publishDate 2020-03-01
description This study was conducted to determine the influence of the oil palm boiler ash (OPBA) reinforcement on the microstructural, physical, mechanical and thermal properties of epoxy polymer composites. The chemical composition analysis of OPBA revealed that it contains about 55 wt.% of SiO2 along with other metallic oxides and elements. The surface morphology of OPBA showed angular and irregular shapes with porous structures. The influence of OPBA as a reinforcement in epoxy composite was studied with varying filler loadings (10–50 wt.%) and different particle sizes (50–150 μm). The result showed that the incorporation of OPBA in composites has improved the physical, mechanical and thermal properties of the epoxy matrix. The highest physical and mechanical properties of fabricated composites were attained with 30 wt.% loading and size of 50 μm. Also, thermal stability and the percentage of char residue of the composite increased with increasing filler loading. Furthermore, the contact angle of OPBA reinforced epoxy composites increased with the increase of filler loading. The lowest value of the contact angle was obtained at 30 wt.% of filler loading with the OPBA particle size of 50 μm. The finding of this study reveals that the OPBA has the potential to be used as reinforcement or filler as well as an alternative of silica-based inorganic fillers used in the enhancement of mechanical, physical and thermal properties of the epoxy polymer composite.
topic Materials science
Agro-industrial waste
Inorganic SiO2
Oil palm boiler ash
Micro filler
Epoxy composites
url http://www.sciencedirect.com/science/article/pii/S2405844020303959
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