Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide
A new macroacyclic amide ligand N,N’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide (BPD), formed by the condensation of 2,6-pyridinedicarbonyldichloride with 2-aminobenzothiazole and its Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes were synthesized. Their structures were elucidated...
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Serbian Chemical Society
2006-01-01
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doaj-c7337f8a3567491f9d015b19009584882020-12-24T14:30:29ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212006-01-0171552954210.2298/JSC0605529G0352-51390605529GSynthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamideGudasi Kalagouda B.0Patil Siddappa A.1Vadavi Ramesh S.2Shenoy Rashmi V.3Patil Manjula S.4P. G. Department of Studies in Chemistry, Karnatak University, DharwadP. G. Department of Studies in Chemistry, Karnatak University, DharwadP. G. Department of Studies in Chemistry, Karnatak University, DharwadP. G. Department of Studies in Chemistry, Karnatak University, DharwadP. G. Department of Studies in Chemistry, Karnatak University, DharwadA new macroacyclic amide ligand N,N’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide (BPD), formed by the condensation of 2,6-pyridinedicarbonyldichloride with 2-aminobenzothiazole and its Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes were synthesized. Their structures were elucidated on the basis of elemental analyses, conductance measurements, magnetic moments, spectral (IR, NMR UV-Visible, EPR and FAB) and thermal studies. The complexes exhibit an octahedral geometry around the metal center. Conductance data of the complexes suggested them to be 1:1 electrolytes. The pentadentate behavior of the ligand was proposed on the basis of spectral studies. The X-band EPR spectra of the Cu(II) and Mn(II) complexes in the polycrystalline state at room (300 K) and liquid nitrogen temperature (77 K) were recorded and their salient features are reported.http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605529G.pdfnn’-bis(2-benzothiazolyl)-26-pyridinedicarboxamide26-pyridinedicarboxylic acid2-aminobenzothiazolespectral studythermal behavior |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Gudasi Kalagouda B. Patil Siddappa A. Vadavi Ramesh S. Shenoy Rashmi V. Patil Manjula S. |
spellingShingle |
Gudasi Kalagouda B. Patil Siddappa A. Vadavi Ramesh S. Shenoy Rashmi V. Patil Manjula S. Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide Journal of the Serbian Chemical Society n n’-bis(2-benzothiazolyl)-2 6-pyridinedicarboxamide 2 6-pyridinedicarboxylic acid 2-aminobenzothiazole spectral study thermal behavior |
author_facet |
Gudasi Kalagouda B. Patil Siddappa A. Vadavi Ramesh S. Shenoy Rashmi V. Patil Manjula S. |
author_sort |
Gudasi Kalagouda B. |
title |
Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide |
title_short |
Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide |
title_full |
Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide |
title_fullStr |
Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide |
title_full_unstemmed |
Synthesis and spectral studies of Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide |
title_sort |
synthesis and spectral studies of cu(ii), ni(ii), co(ii), mn(ii), zn(ii) and cd(ii) complexes of a new macroacyclic ligand n,n’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide |
publisher |
Serbian Chemical Society |
series |
Journal of the Serbian Chemical Society |
issn |
0352-5139 1820-7421 |
publishDate |
2006-01-01 |
description |
A new macroacyclic amide ligand N,N’-bis(2-benzothiazolyl)-2,6-pyridinedicarboxamide (BPD), formed by the condensation of 2,6-pyridinedicarbonyldichloride with 2-aminobenzothiazole and its Cu(II), Ni(II), Co(II), Mn(II), Zn(II) and Cd(II) complexes were synthesized. Their structures were elucidated on the basis of elemental analyses, conductance measurements, magnetic moments, spectral (IR, NMR UV-Visible, EPR and FAB) and thermal studies. The complexes exhibit an octahedral geometry around the metal center. Conductance data of the complexes suggested them to be 1:1 electrolytes. The pentadentate behavior of the ligand was proposed on the basis of spectral studies. The X-band EPR spectra of the Cu(II) and Mn(II) complexes in the polycrystalline state at room (300 K) and liquid nitrogen temperature (77 K) were recorded and their salient features are reported. |
topic |
n n’-bis(2-benzothiazolyl)-2 6-pyridinedicarboxamide 2 6-pyridinedicarboxylic acid 2-aminobenzothiazole spectral study thermal behavior |
url |
http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605529G.pdf |
work_keys_str_mv |
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