Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]

Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]

The polymeric title compound, {[Dy2(C8H4O5)3(C10H8N2)2(H2O)2]·2H2O}n, contains two independent DyIII ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One DyIII ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and...

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Main Author: Yan-Lin Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811039080
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spelling doaj-cfa6d503ae7146039834e09bd343ba5b2020-11-25T01:09:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1473m147410.1107/S1600536811039080Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]Yan-Lin ZhangThe polymeric title compound, {[Dy2(C8H4O5)3(C10H8N2)2(H2O)2]·2H2O}n, contains two independent DyIII ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One DyIII ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The DyIII ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H...O hydrogen bonds are present in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811039080
collection DOAJ
language English
format Article
sources DOAJ
author Yan-Lin Zhang
spellingShingle Yan-Lin Zhang
Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]
Acta Crystallographica Section E
author_facet Yan-Lin Zhang
author_sort Yan-Lin Zhang
title Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]
title_short Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]
title_full Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]
title_fullStr Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]
title_full_unstemmed Poly[[diaquabis(2,2′-bipyridine-κ2N,N′)(μ3-5-hydroxyisophthalato-κ5O1,O1′:O3,O3′:O3′)(μ3-5-hydroxyisophthalato-κ4O1,O1′:O3:O3′)(μ2-5-hydroxyisophthalato-κ3O1,O1′:O3)didysprosium(III)] dihydrate]
title_sort poly[[diaquabis(2,2′-bipyridine-κ2n,n′)(μ3-5-hydroxyisophthalato-κ5o1,o1′:o3,o3′:o3′)(μ3-5-hydroxyisophthalato-κ4o1,o1′:o3:o3′)(μ2-5-hydroxyisophthalato-κ3o1,o1′:o3)didysprosium(iii)] dihydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description The polymeric title compound, {[Dy2(C8H4O5)3(C10H8N2)2(H2O)2]·2H2O}n, contains two independent DyIII ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One DyIII ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The DyIII ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H...O hydrogen bonds are present in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811039080
work_keys_str_mv AT yanlinzhang polydiaquabis22amp8242bipyridineamp9542nnamp8242amp95635hydroxyisophthalatoamp9545o1o1amp8242o3o3amp8242o3amp8242amp95635hydroxyisophthalatoamp9544o1o1amp8242o3o3amp8242amp95625hydroxyisophthalatoamp9543o1o1amp8242o3didysprosiumiiidihydrate
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