Synthesis of 6,12-Disubstituted Methanodibenzo[<i>b</i>,<i>f</i>][1,5]dioxocins: Pyrrolidine Catalyzed Self-Condensation of 2′-Hydroxyacetophenones

Synthesis of 6,12-Disubstituted Methanodibenzo[<i>b</i>,<i>f</i>][1,5]dioxocins: Pyrrolidine Catalyzed Self-Condensation of 2′-Hydroxyacetophenones

The preparation of unprecedented 6,12-disubstituted methanodibenzo[<i>b</i>,<i>f</i>][1,5]dioxocins from pyrrolidine catalyzed self-condensation of 2′-hydroxyacetophenones is herein described. This method provides easy access to this highly bridged complex core, resulting in...

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Bibliographic Details
Main Authors: Benedicta Assoah, Vesa Riihonen, João R. Vale, Arto Valkonen, Nuno R. Candeias
Format: Article
Language:English
Published: MDPI AG 2019-06-01
Series:Molecules
Subjects:
enamine
1,5-dioxocin
self-condensation
2′-hydroxyacetophenone
Online Access:https://www.mdpi.com/1420-3049/24/13/2405

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