Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate

Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate

In the molecule of the title N,N′-disubstituted imidazol-2-ylidene palladium(II) complex, [PdBr2(C21H24N4O)]·CH2Cl2, the palladium(II) atom adopts a slightly distorted square-planar coordination (r.m.s. deviation = 0.0145 Å), and the five-membered chelate ring is almost planar [maximum displacement...

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Bibliographic Details
Main Authors: Qilin Liu, Pu Mao, Jinwei Yuan, Yongmei Xiao, Liangru Yang
Format: Article
Language:English
Published: International Union of Crystallography 2019-07-01
Series:IUCrData
Subjects:
crystal structure
imidazol-2-ylidene
palladium
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461900899X
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spelling doaj-d7cc625cf7134833908433648e8bb7b02020-11-24T21:16:19ZengInternational Union of CrystallographyIUCrData2414-31462019-07-0147x19089910.1107/S241431461900899Xrz4032Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvateQilin Liu0Pu Mao1Jinwei Yuan2Yongmei Xiao3Liangru Yang4College of Chemistry and Chemical engineering, Henan University of Technology, Zhengzhou 450001, People's Republic of ChinaCollege of Chemistry and Chemical engineering, Henan University of Technology, Zhengzhou 450001, People's Republic of ChinaCollege of Chemistry and Chemical engineering, Henan University of Technology, Zhengzhou 450001, People's Republic of ChinaCollege of Chemistry and Chemical engineering, Henan University of Technology, Zhengzhou 450001, People's Republic of ChinaCollege of Chemistry and Chemical engineering, Henan University of Technology, Zhengzhou 450001, People's Republic of ChinaIn the molecule of the title N,N′-disubstituted imidazol-2-ylidene palladium(II) complex, [PdBr2(C21H24N4O)]·CH2Cl2, the palladium(II) atom adopts a slightly distorted square-planar coordination (r.m.s. deviation = 0.0145 Å), and the five-membered chelate ring is almost planar [maximum displacement = 0.015 (8) Å]. The molecular conformation is enforced by intramolecular C—H...Br hydrogen bonds. In the crystal, complex molecules and dichloromethane molecules are linked into a three-dimensional network by C—H...O and C—H...Br hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S241431461900899Xcrystal structureimidazol-2-ylidenepalladium
collection DOAJ
language English
format Article
sources DOAJ
author Qilin Liu
Pu Mao
Jinwei Yuan
Yongmei Xiao
Liangru Yang
spellingShingle Qilin Liu
Pu Mao
Jinwei Yuan
Yongmei Xiao
Liangru Yang
Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate
IUCrData
crystal structure
imidazol-2-ylidene
palladium
author_facet Qilin Liu
Pu Mao
Jinwei Yuan
Yongmei Xiao
Liangru Yang
author_sort Qilin Liu
title Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate
title_short Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate
title_full Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate
title_fullStr Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate
title_full_unstemmed Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate
title_sort dibromido[n-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-n′-(pyridin-2-yl)imidazol-2-ylidene]palladium(ii) dichloromethane monosolvate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2019-07-01
description In the molecule of the title N,N′-disubstituted imidazol-2-ylidene palladium(II) complex, [PdBr2(C21H24N4O)]·CH2Cl2, the palladium(II) atom adopts a slightly distorted square-planar coordination (r.m.s. deviation = 0.0145 Å), and the five-membered chelate ring is almost planar [maximum displacement = 0.015 (8) Å]. The molecular conformation is enforced by intramolecular C—H...Br hydrogen bonds. In the crystal, complex molecules and dichloromethane molecules are linked into a three-dimensional network by C—H...O and C—H...Br hydrogen bonds.
topic crystal structure
imidazol-2-ylidene
palladium
url http://scripts.iucr.org/cgi-bin/paper?S241431461900899X
work_keys_str_mv AT qilinliu dibromidon1diethylamino1oxo3phenylpropan2ylnpyridin2ylimidazol2ylidenepalladiumiidichloromethanemonosolvate
AT pumao dibromidon1diethylamino1oxo3phenylpropan2ylnpyridin2ylimidazol2ylidenepalladiumiidichloromethanemonosolvate
AT jinweiyuan dibromidon1diethylamino1oxo3phenylpropan2ylnpyridin2ylimidazol2ylidenepalladiumiidichloromethanemonosolvate
AT yongmeixiao dibromidon1diethylamino1oxo3phenylpropan2ylnpyridin2ylimidazol2ylidenepalladiumiidichloromethanemonosolvate
AT liangruyang dibromidon1diethylamino1oxo3phenylpropan2ylnpyridin2ylimidazol2ylidenepalladiumiidichloromethanemonosolvate
_version_ 1726016054130376704

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