SYNTHESIS OF TRIPHENYLAMINE-BASED RHOMBIMINE MACROCYCLE BY [2+2] CYCLOCONDENSATION REACTION BETWEEN (1R,2R)-DIAMINOCYCLOHEXANE AND 4,4’-DIFORMYL TRIPHENYLAMINE

SYNTHESIS OF TRIPHENYLAMINE-BASED RHOMBIMINE MACROCYCLE BY [2+2] CYCLOCONDENSATION REACTION BETWEEN (1R,2R)-DIAMINOCYCLOHEXANE AND 4,4’-DIFORMYL TRIPHENYLAMINE

A Schiff base macrocycle with persistent rhomboidal shape was synthesized in excellent yield through [2+2] condensation reaction between (R,R)-1,2-diaminocyclohexane and 4,4’-diformyltriphenylamine. The dimeric macrocylic structure was proved by electrospray ionization mass spectrometry (ESI-MS), 1H...

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Bibliographic Details
Main Authors: Loredana Vacareanu (Stafie), Virgil Barboiu, Daniel Timpu, Mircea Grigoras
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2009-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
triphenylamine group
Schiff base macrocycle
rhombimine
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/Vacareanu%2097-102.pdf

Internet

http://www.cjm.asm.md/sites/default/files/article_files/Vacareanu%2097-102.pdf

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