Catalytic Asymmetric Nitro-Mannich Reactions with a Yb/K Heterobimetallic Catalyst

A catalytic asymmetric nitro-Mannich (aza-Henry) reaction with rare earth metal/alkali metal heterobimetallic catalysts is described. A Yb/K heterobimetallic catalyst assembled by an amide-based ligand promoted the asymmetric nitro-Mannich reaction to afford enantioenriched anti-b-nitroamines in up...

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Bibliographic Details
Main Authors: Tatsuya Nitabaru, Naoya Kumagai, Masakatsu Shibasaki
Format: Article
Language:English
Published: MDPI AG 2010-03-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/15/3/1280/