Thermodynamic modeling of ternary liquid-liquid systems with forming immiscibility islands

Thermodynamic modeling of ternary liquid-liquid systems with forming immiscibility islands

The aim of this work was to study the application of a stochastic algorithm to correlate the experimental data of island-type systems in ternary systems. Thermodynamic NRTL and UNIQUAC models were used to evaluate the activity coefficients. Results regarding the application of the stochastic algorit...

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Bibliographic Details
Main Authors: Andre Zuber, Rodrigo Raimundo, Marcos Rogério Mafra, Lúcio Cardozo Filho, José Vladimir Oliveira, Marcos Lúcio Corazza
Format: Article
Language:English
Published: Instituto de Tecnologia do Paraná (Tecpar) 2013-12-01
Series:Brazilian Archives of Biology and Technology
Subjects:
LLE
island-type
stochastic algorithm
NRTL
UNIQUAC
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132013000600020&lng=en&tlng=en
Description
Summary:The aim of this work was to study the application of a stochastic algorithm to correlate the experimental data of island-type systems in ternary systems. Thermodynamic NRTL and UNIQUAC models were used to evaluate the activity coefficients. Results regarding the application of the stochastic algorithm were in good agreement with those presented in the current literature. However, generalization of the method proposed in the present work remained an intriguing and complex task so as to reach broad conclusions.
ISSN:1678-4324

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