An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one

An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one

The title compound, C16H10Cl2O3, is almost planar with a dihedral angle of 0.14 (16)° between the benzodioxole ring system and the dichlorobenzene ring that are bridged by the olefinic double bond. The corresponding value reported for the monoclinic polymorph is [5.57 (9)° (Lokeshwari et al. (2017)....

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Main Authors: S. Naveen, A. Dileep Kumar, M. V. Deepa Urs, K. Ajay Kumar, N. K. Lokanath, Ismail Warad
Format: Article
Language:English
Published: International Union of Crystallography 2017-11-01
Series:IUCrData
Subjects:
crystal structure
chalcone
E configuration
hydrogen bonds
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314617015905
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spelling doaj-dd67d6fc120e409684692f8474975bf82020-11-24T23:01:56ZengInternational Union of CrystallographyIUCrData2414-31462017-11-01211x17159010.1107/S2414314617015905sj4143An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-oneS. Naveen0A. Dileep Kumar1M. V. Deepa Urs2K. Ajay Kumar3N. K. Lokanath4Ismail Warad5Department of Physics, School of Engineering & Technology, Jain University, Bangalore 562 112, IndiaDepartment of Chemistry, Yuvaraja's College, University of Mysore, Mysuru 570 005, IndiaDepartment of Physics, National Institute of Engineering, Mysuru 570 008, IndiaDepartment of Chemistry, Yuvaraja's College, University of Mysore, Mysuru 570 005, IndiaDepartment of Studies in Physics, University of Mysore, Manasagangotri, Mysuru 570 006, IndiaDepartment of Chemistry, Science College, An-Najah National University, PO Box 7, Nablus, West Bank, Palestinian TerritoriesThe title compound, C16H10Cl2O3, is almost planar with a dihedral angle of 0.14 (16)° between the benzodioxole ring system and the dichlorobenzene ring that are bridged by the olefinic double bond. The corresponding value reported for the monoclinic polymorph is [5.57 (9)° (Lokeshwari et al. (2017). IUCrData, 2, x170103). The carbonyl group lies almost in the plane of the olefinic double bond and is twisted slightly from the benzodioxole ring plane. In the crystal, the molecules are linked by weak C—H...O and C—H...Cl hydrogen bonds, forming a chain propagating along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2414314617015905crystal structurechalconeE configurationhydrogen bonds
collection DOAJ
language English
format Article
sources DOAJ
author S. Naveen
A. Dileep Kumar
M. V. Deepa Urs
K. Ajay Kumar
N. K. Lokanath
Ismail Warad
spellingShingle S. Naveen
A. Dileep Kumar
M. V. Deepa Urs
K. Ajay Kumar
N. K. Lokanath
Ismail Warad
An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
IUCrData
crystal structure
chalcone
E configuration
hydrogen bonds
author_facet S. Naveen
A. Dileep Kumar
M. V. Deepa Urs
K. Ajay Kumar
N. K. Lokanath
Ismail Warad
author_sort S. Naveen
title An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
title_short An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
title_full An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
title_fullStr An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
title_full_unstemmed An orthorhombic polymorph of (E)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
title_sort orthorhombic polymorph of (e)-1-(benzo[d][1,3]dioxol-5-yl)-3-(2,3-dichlorophenyl)prop-2-en-1-one
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2017-11-01
description The title compound, C16H10Cl2O3, is almost planar with a dihedral angle of 0.14 (16)° between the benzodioxole ring system and the dichlorobenzene ring that are bridged by the olefinic double bond. The corresponding value reported for the monoclinic polymorph is [5.57 (9)° (Lokeshwari et al. (2017). IUCrData, 2, x170103). The carbonyl group lies almost in the plane of the olefinic double bond and is twisted slightly from the benzodioxole ring plane. In the crystal, the molecules are linked by weak C—H...O and C—H...Cl hydrogen bonds, forming a chain propagating along the b-axis direction.
topic crystal structure
chalcone
E configuration
hydrogen bonds
url http://scripts.iucr.org/cgi-bin/paper?S2414314617015905
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