Mechanochemical borylation of aryldiazonium salts; merging light and ball milling
Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the c...
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Beilstein-Institut
2017-07-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.13.144 |
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doaj-e20beb421e0140ca9e6a27f79c7fbf3f2021-02-02T00:18:41ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972017-07-011311463146910.3762/bjoc.13.1441860-5397-13-144Mechanochemical borylation of aryldiazonium salts; merging light and ball millingJosé G. Hernández0Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, D-52074 Aachen, GermanyMerging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the catalyst-free liquid-assisted grinding/irradiation reaction also led to product formation, featuring a direct photolysis pathway facilitated by substrate–solvent charge-transfer complex formation.https://doi.org/10.3762/bjoc.13.144aryldiazonium saltsborylationeosin Ymechanochemistryphotocatalysis |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
José G. Hernández |
| spellingShingle |
José G. Hernández Mechanochemical borylation of aryldiazonium salts; merging light and ball milling Beilstein Journal of Organic Chemistry aryldiazonium salts borylation eosin Y mechanochemistry photocatalysis |
| author_facet |
José G. Hernández |
| author_sort |
José G. Hernández |
| title |
Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_short |
Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_full |
Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_fullStr |
Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_full_unstemmed |
Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_sort |
mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| publisher |
Beilstein-Institut |
| series |
Beilstein Journal of Organic Chemistry |
| issn |
1860-5397 |
| publishDate |
2017-07-01 |
| description |
Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the catalyst-free liquid-assisted grinding/irradiation reaction also led to product formation, featuring a direct photolysis pathway facilitated by substrate–solvent charge-transfer complex formation. |
| topic |
aryldiazonium salts borylation eosin Y mechanochemistry photocatalysis |
| url |
https://doi.org/10.3762/bjoc.13.144 |
| work_keys_str_mv |
AT joseghernandez mechanochemicalborylationofaryldiazoniumsaltsmerginglightandballmilling |
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1724314106775732224 |