trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)

trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)

The title complex, [RhCl(C21H21O3P)2(CO)], is a rhodium analogue to Vaska's complex with para-methoxy substituents on the six phosphanyl–aryl units. Two independent molecules are present in the unit cell, with their metal atoms both located on an inversion centre. This causes the...

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Main Authors: Stefan Warsink, Andreas Roodt
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811046150
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spelling doaj-e49daa6fd0f04e65adecf7d84e892ae22020-11-25T02:07:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1695m169610.1107/S1600536811046150trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)Stefan WarsinkAndreas RoodtThe title complex, [RhCl(C21H21O3P)2(CO)], is a rhodium analogue to Vaska's complex with para-methoxy substituents on the six phosphanyl–aryl units. Two independent molecules are present in the unit cell, with their metal atoms both located on an inversion centre. This causes the chloride and carbonyl ligands to exhibit a positional disorder in a 0.5:0.5 ratio. The two RhI atoms exhibit a distorted square-planar geometry. There are a few weak intramolecular C—H...X interactions (X = O, Cl). Interestingly, no significant intermolecular interactions are found between the two independent molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536811046150
collection DOAJ
language English
format Article
sources DOAJ
author Stefan Warsink
Andreas Roodt
spellingShingle Stefan Warsink
Andreas Roodt
trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)
Acta Crystallographica Section E
author_facet Stefan Warsink
Andreas Roodt
author_sort Stefan Warsink
title trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)
title_short trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)
title_full trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)
title_fullStr trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)
title_full_unstemmed trans-Carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κP]rhodium(I)
title_sort trans-carbonylchloridobis[tris(4-methoxyphenyl)phosphane-κp]rhodium(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description The title complex, [RhCl(C21H21O3P)2(CO)], is a rhodium analogue to Vaska's complex with para-methoxy substituents on the six phosphanyl–aryl units. Two independent molecules are present in the unit cell, with their metal atoms both located on an inversion centre. This causes the chloride and carbonyl ligands to exhibit a positional disorder in a 0.5:0.5 ratio. The two RhI atoms exhibit a distorted square-planar geometry. There are a few weak intramolecular C—H...X interactions (X = O, Cl). Interestingly, no significant intermolecular interactions are found between the two independent molecules.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811046150
work_keys_str_mv AT stefanwarsink transcarbonylchloridobistris4methoxyphenylphosphaneamp954prhodiumi
AT andreasroodt transcarbonylchloridobistris4methoxyphenylphosphaneamp954prhodiumi
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