(E)-2-[(2,4,6-Trimethoxybenzylidene)- amino]phenol

There are two independent molecules in the asymmetric unit of the title compound, C16H17NO4, with similar conformations but some differences in their bond angles. Each molecule adopts a trans configuration with respect to the methylidene C N bond and is twisted with a dihedral angle between the two...

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Bibliographic Details
Main Authors: Kaewmanee, Narissara (Author), Chantrapromma, Suchada (Author), Boonnak, Nawong (Author), Ching, Kheng Quah (Author), Fun, Hoong Kun (Author)
Format: Article
Language:English
Published: International Union of Crystallography, 2014-01.
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Summary:There are two independent molecules in the asymmetric unit of the title compound, C16H17NO4, with similar conformations but some differences in their bond angles. Each molecule adopts a trans configuration with respect to the methylidene C N bond and is twisted with a dihedral angle between the two substituted benzene rings of 80.52 (7)� in one molecule and 83.53 (7)� in the other. All methoxy groups are approximately coplanar with the attached benzene rings, with Cmethyl-O-C-C torsion angles ranging from �6.7 (2) to 5.07 (19)�. In the crystal, independent molecules are linked together by O-H� � �N and O-H� � �O hydrogen bonds and a �-� interaction [centroid-centroid distance of 3.6030 (9) A ° ], forming a dimer. The dimers are further linked by weak C- H� � �O interactions and another �-� interaction [centroid- centroid distance of 3.9452 (9) A ° ] into layers lying parallel to the ab plane.