Ligand-Based Reduction of CO2 to CO Mediated by an Anionic Niobium Nitride Complex
The terminal nitride anion complex [Na][N≡Nb(N[tBu]Ar)3] ([Na][1], Ar = 3,5-Me2C6H3) reacts quantitatively with CO2 to give the carbamate complex [Na][O2CN≡Nb(N[tBu]Ar)3] ([Na][O2C-1]). The structure of [Na][O2C-1] as the bis-12-crown-4 solvate, as determined by X-ray crystallography, displays a uni...
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society,
2011-08-16T13:24:33Z.
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| Online Access: | Get fulltext |