Triptycene Diols: A Strategy for Synthesizing Planar pi Systems through Catalytic Conversion of a Poly(p-phenylene ethynylene) into a Poly(p-phenylene vinylene)
At level best: A strategic synthesis of a new class of poly(p-phenylene vinylene)-bearing annulated alkene units from a parent poly(p-phenylene ethynylene) is described (see scheme). The gold-mediated cycloisomerization reaction of alkynes with appended hydroxy-group reacting partners delivers produ...
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Format: | Article |
Language: | English |
Published: |
Wiley Blackwell,
2012-10-24T17:01:55Z.
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Subjects: | |
Online Access: | Get fulltext |