| Summary: | 碩士 === 中國文化大學 === 生活應用科學研究所碩士在職專班 === 92 === The present studies aredivide into parts of I and II.：Part I The synthesis of mononuclear copper(II) complexes.Part II The reactive activities of catecholase-like.
Part I The synthesis of mononuclear copper(II) complexes
1. L1
The ligands containing Schiff，s base,derived from 1,3-diaminopropane-2-ol and salicyaldehyde.
2.[CuL1]
A methanolic solution of L1 was slowly added to a stirred methanolic solution of copper(II) perchlorate hexahydrate.The resulation solution was reduced in volume to complete the precipitation of micro-crystalline.
3, [CuL2]
A methanolic solution of salicyaldehyde was slowly added to a stirred methanolic solution of copper(II) perchlorate hexahydrate.The resulation solution was reduced in volume to complete the precipitation of micro-crystalline.
4. [CuL3]
A methanolic solution of aceylaceton was slowly added to a stirred methanolic solution of copper(II) perchlorate hexahydrate.The resulation solution was reduced in volume to complete the precipitation of micro-crystalline.
5. [CuL4]
A methanolic solution of benzoylaceton was slowly added to a stirred methanolic solution of copper(II) perchlorate hexahydrate.The resulation solution was reduced in volume to complete the precipitation of micro-crystalline.
Part II The reactive activities of catecholase-like.
. Theoretically,the mononuclear copper(II) compexes will be found to be readily reduced to copper(I) complexes by 3,5-di-tert-butycatechol (dtbc).The reaction of copper (II) complexes in MeOH have been studies. The dtbc will be oxidized to quinone,and characterized by absorption band of UV-VIS spectra.
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