Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex

碩士 === 國立中山大學 === 化學系研究所 === 104 === Reaction of C80H14N2O2(2’) with Mo(CO)6 in refluxing chlorobenzene, produced Mo(CO)3η4-(C63NPh2Py) (3). Compound( 3) occurred C=O bond activation, than the diketone group ligand eliminated two oxygen atoms to generate the olefin, which mimics the organic McMurry...

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Main Authors: Yi-Min Lin, 林毅旻
Other Authors: Wen-Yann Yeh
Format: Others
Language:zh-TW
Published: 2016
Online Access:http://ndltd.ncl.edu.tw/handle/72579012244556067426
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spelling ndltd-TW-104NSYS50650832017-07-30T04:41:15Z http://ndltd.ncl.edu.tw/handle/72579012244556067426 Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex 開環富勒烯與鉬羰基化合物之反應性研究 Yi-Min Lin 林毅旻 碩士 國立中山大學 化學系研究所 104 Reaction of C80H14N2O2(2’) with Mo(CO)6 in refluxing chlorobenzene, produced Mo(CO)3η4-(C63NPh2Py) (3). Compound( 3) occurred C=O bond activation, than the diketone group ligand eliminated two oxygen atoms to generate the olefin, which mimics the organic McMurry reaction. Complex (3) has been characterized by IR, NMR, Mass spectroscopy, and single-crystal、X-ray diffraction study. Wen-Yann Yeh 葉文彥 2016 學位論文 ; thesis 74 zh-TW
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description 碩士 === 國立中山大學 === 化學系研究所 === 104 === Reaction of C80H14N2O2(2’) with Mo(CO)6 in refluxing chlorobenzene, produced Mo(CO)3η4-(C63NPh2Py) (3). Compound( 3) occurred C=O bond activation, than the diketone group ligand eliminated two oxygen atoms to generate the olefin, which mimics the organic McMurry reaction. Complex (3) has been characterized by IR, NMR, Mass spectroscopy, and single-crystal、X-ray diffraction study.
author2 Wen-Yann Yeh
author_facet Wen-Yann Yeh
Yi-Min Lin
林毅旻
author Yi-Min Lin
林毅旻
spellingShingle Yi-Min Lin
林毅旻
Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
author_sort Yi-Min Lin
title Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
title_short Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
title_full Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
title_fullStr Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
title_full_unstemmed Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
title_sort reactions of open-cage fullerene with molybdenum carbonyl complex
publishDate 2016
url http://ndltd.ncl.edu.tw/handle/72579012244556067426
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