Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs)
碩士 === 國立中央大學 === 化學工程與材料工程學系 === 105 === In this study, conventional electric and microwave-assisted heating were used for metal-organic framework synthesis, and we attempted to grow MIL-53 (Al) membrane on α-Al2O3 via vapor processing. Different from conventional method which places α-Al2O3 in the...
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ndltd-TW-105NCU050630182017-10-22T04:29:51Z http://ndltd.ncl.edu.tw/handle/32753197458387320344 Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) 蒸氣相成長金屬有機框架材料合成 Bo-Rong Wu 吳柏融 碩士 國立中央大學 化學工程與材料工程學系 105 In this study, conventional electric and microwave-assisted heating were used for metal-organic framework synthesis, and we attempted to grow MIL-53 (Al) membrane on α-Al2O3 via vapor processing. Different from conventional method which places α-Al2O3 in the liquid precursor solution for preparing inorganic gas separation membrane, these methods are inexpensive for membrane fabrication in the vapor phase condition. In this research, we developed four methods for membrane synthesis in the vapor phase. The membrane coverage and uniformity were improved by adjusting the experimental process and parameters. In addition, membrane synthesis with different conditions resulted in different crystal morphologies, such as bulk-like and rod-like crystals. Namely, we could control the membrane morphology by synthetic methods and phases. Material growing on α-Al2O3 was identified by X-ray diffraction (XRD). Scanning electron microscopy (SEM) was used for morphology analysis. Different surface area of MIL-53 (Al) synthesized by conventional electric and microwave-assisted heating was confirmed by BET surface area measurement. Bor Kae Chang 張博凱 2017 學位論文 ; thesis 104 en_US |
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碩士 === 國立中央大學 === 化學工程與材料工程學系 === 105 === In this study, conventional electric and microwave-assisted heating were used for metal-organic framework synthesis, and we attempted to grow MIL-53 (Al) membrane on α-Al2O3 via vapor processing. Different from conventional method which places α-Al2O3 in the liquid precursor solution for preparing inorganic gas separation membrane, these methods are inexpensive for membrane fabrication in the vapor phase condition.
In this research, we developed four methods for membrane synthesis in the vapor phase. The membrane coverage and uniformity were improved by adjusting the experimental process and parameters. In addition, membrane synthesis with different conditions resulted in different crystal morphologies, such as bulk-like and rod-like crystals. Namely, we could control the membrane morphology by synthetic methods and phases.
Material growing on α-Al2O3 was identified by X-ray diffraction (XRD). Scanning electron microscopy (SEM) was used for morphology analysis. Different surface area of MIL-53 (Al) synthesized by conventional electric and microwave-assisted heating was confirmed by BET surface area measurement.
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author2 |
Bor Kae Chang |
author_facet |
Bor Kae Chang Bo-Rong Wu 吳柏融 |
author |
Bo-Rong Wu 吳柏融 |
spellingShingle |
Bo-Rong Wu 吳柏融 Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) |
author_sort |
Bo-Rong Wu |
title |
Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) |
title_short |
Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) |
title_full |
Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) |
title_fullStr |
Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) |
title_full_unstemmed |
Vapor Phase Synthesis of Metal-Organic Frameworks (MOFs) |
title_sort |
vapor phase synthesis of metal-organic frameworks (mofs) |
publishDate |
2017 |
url |
http://ndltd.ncl.edu.tw/handle/32753197458387320344 |
work_keys_str_mv |
AT borongwu vaporphasesynthesisofmetalorganicframeworksmofs AT wúbǎiróng vaporphasesynthesisofmetalorganicframeworksmofs AT borongwu zhēngqìxiāngchéngzhǎngjīnshǔyǒujīkuāngjiàcáiliàohéchéng AT wúbǎiróng zhēngqìxiāngchéngzhǎngjīnshǔyǒujīkuāngjiàcáiliàohéchéng |
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1718556499863666688 |