Generation and reactions of thionitroso and thioxophosphine intermediates

A series of alkylthionitroso compounds have been generated via thermal fragmentation of N-chlorothio-N-trimethylsilylalkylamines and intercepted with dienes to form 1,2-thiazine heterocycles (via Diels-Alder reaction) and N-alkylsulfenamides (via Ene reaction). Both types of product were found to be...

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Bibliographic Details
Main Author: Mckelvey, Graham Neil
Published: Durham University 1995
Subjects:
547
Online Access:http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295000