Part I. The chemistry of a planar cyclooctatetraene derivative fused to phenanthrene ring: and Part II. Regiospecific synthesis of 2,3-disubstituted and 2,3,5-trisubstituted furans from 2,4-bis(trimethylsilyl)furan.

• Other Authors: Leung, Chun-yip.
• Format: Others
• Language: English
• Published: Chinese University of Hong Kong 1993
• Subjects: Phenanthrene; Cyclooctatetraene; Benzene; Furans
• Online Access: http://library.cuhk.edu.hk/record=b5887840; http://repository.lib.cuhk.edu.hk/en/item/cuhk-319183

by Chun-yip Leung. === Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. === Includes bibliographical references (leaves 72-76). === Acknowledgements --- p.1 === Chapter Part 1). --- The Chemistry of A Planar Cyclooctatetraene Derivatives Fused to Phenanthrene Ring --- p.2 === Chapter (I). --- Abstract --- p.2 === Chapter (II). --- Introduction --- p.3 === Chapter (III). --- Results and Discussion --- p.9 === Chapter (IV). --- Conclusion --- p.18 === Chapter (V). --- Experimental Section --- p.19 === Chapter Part 2). --- "Regiospecific Synthesis of 2,3-Disubstituted and 2,3,5-Trisubstituted Furans from 2,4-Bis(trimethyl- silyl)furan" --- p.28 === Chapter (I). --- Abstract --- p.28 === Chapter (II). --- Introduction --- p.29 === Chapter (A). --- Reactions of Furan --- p.29 === Chapter (1). --- Reactions with Electrophiles --- p.29 === Chapter (2). --- Reactions with Nucleophiles --- p.30 === Chapter (3). --- Cycloaddition Reactions --- p.31 === Chapter (B). --- Synthesis of Polysubstituted Furans --- p.32 === Chapter (1). --- By Ag(I)-Catalyzed Cyclization --- p.33 === Chapter (2). --- By Base-Catalyzed Isomerization of Alkynyloxiranes --- p.33 === Chapter (3). --- By Base-Catalyzed Cyclization- Isomerization of γ-Alkynyl Allylic Alcohol --- p.36 === Chapter (4). --- "By Palladium-Catalyzed Coupling of 2- Propargyl-l,3-dicarbonyl Compounds and Vinylic, Aryl Triflates or Halide" --- p.36 === Chapter (5). --- "From α,β-Unsaturated Ketones" --- p.38 === Chapter (C). --- Recent Achievement --- p.39 === Chapter (III). --- Results and Discussion --- p.44 === Chapter (A). --- "Attempted Synthesis of 2,4-Disubstituted Furans" --- p.44 === Chapter (B). --- "Synthesis of 2,3,5-Trisubstituted Furans" --- p.45 === Chapter (1). --- Synthesis of 2-benzyl-3-m-anisyl-5- p-tolyl-furan (30) --- p.45 === Chapter (2). --- Synthesis of 2-benzyl-3-trans-hexen- l-yl-5-p-tolyl-furan (31) --- p.51 === Chapter (3). --- "Synthesis of 2-(3,5-dimethyl)benzyl-3- p-methoxycarbonylbenzyl-5-hexyl- furan (32)" --- p.52 === Chapter (4). --- "Synthesis of 2-benzyl-3-[3,4-(methyl- enedioxy)]benzyl-furan (33)" --- p.57 === Chapter (IV). --- Conclusion --- p.60 === Chapter (V). --- Experimental Section --- p.61 === References --- p.7 2 === List of Spectra --- p.7 7 === Spectra --- p.7 9