Synthesis and X-ray Diffraction Structures of 2-(2-thienylidene)-4,5-bis-(diphenylphosphino)-4-cyclopenten-1,3-dione and fac-BrRe(CO)3[2-(2-thienylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione]

Synthesis and X-ray Diffraction Structures of 2-(2-thienylidene)-4,5-bis-(diphenylphosphino)-4-cyclopenten-1,3-dione and fac-BrRe(CO)3[2-(2-thienylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione]

Treatment of 4,5 bis-(diphenylphosphino)-cyclopenten-1,3 dione with thiophene carboxyaldehyde in dichloromethane, in the presence of molecular sieves results in a new heterocyclic compound, 2-(2-thienylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (ligand), with a high yield. This produc...

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Bibliographic Details
Main Author: Pingali, Aparna
Other Authors: Richmond, Michael
Format: Others
Language:English
Published: University of North Texas 2005
Subjects:
Metal clusters.
Ligands.
Organometallic compounds.
phosphine ligands
rhenium THF derivative
fac-BrRe(CO)3(bma)
Online Access:https://digital.library.unt.edu/ark:/67531/metadc4942/

Internet

https://digital.library.unt.edu/ark:/67531/metadc4942/

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