Enhancement of sonochemical production of hydroxyl radicals from pulsed cylindrically converging ultrasound waves

Sonochemistry is the use of ultrasound to generate highly reactive radical species through the inertial collapse of a gas/vapour cavity and is a green alternative for hydrogen production, wastewater treatment, and chemical synthesis and modifications. Yet, current sonochemical reactors often are lim...

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書目詳細資料
發表在:Ultrasonics Sonochemistry
Main Authors: Cherie C.Y. Wong, Jason L. Raymond, Lillian N. Usadi, Zhiyuan Zong, Stephanie C. Walton, Adam C. Sedgwick, James Kwan
格式: Article
語言:英语
出版: Elsevier 2023-10-01
主題:
在線閱讀:http://www.sciencedirect.com/science/article/pii/S1350417723002717
實物特徵
總結:Sonochemistry is the use of ultrasound to generate highly reactive radical species through the inertial collapse of a gas/vapour cavity and is a green alternative for hydrogen production, wastewater treatment, and chemical synthesis and modifications. Yet, current sonochemical reactors often are limited by their design, resulting in low efficacy and yields with slow reaction kinetics. Here, we constructed a novel sonochemical reactor design that creates cylindrically converging ultrasound waves to create an intense localised region of high acoustic pressure amplitudes (15 MPaPKPK) capable of spontaneously nucleating cavitation. Using a novel dosimetry technique, we determined the effect of acoustic parameters on the yield of hydroxyl radicals (HO·), HO· production rate, and ultimately the sonochemical efficiency (SE) of our reactor. Our reactor design had a significantly higher HO· production rate and SE compared to other conventional reactors and across literature.
ISSN:1350-4177